Bis(triphenyltin) oxide

Base Information

• Chemical Name: Bis(triphenyltin) oxide
• CAS No.: 1262-21-1
• Molecular Formula: C36H30OSn2
• Molecular Weight: 716.054
• Hs Code.: 29310099
• European Community (EC) Number: 215-025-4
• DSSTox Substance ID: DTXSID4074485
• NSC Number: 113258
• Wikidata: Q82002810
• Mol file: 1262-21-1.mol

Synonyms:Bis(triphenyltin) oxide;1262-21-1;Distannoxane, hexaphenyl-;Bis(triphenyltin)oxide;triphenyl(triphenylstannyloxy)stannane;Distannoxane, 1,1,1,3,3,3-hexaphenyl-;Fentin-oxide;EINECS 215-025-4;NSC 113258;triphenyl[(triphenylstannyl)oxy]stannane;Bis(triphenylzinn)-oxid;starbld0016552;AI3-60284;SCHEMBL2017225;?BIS(TRIPHENYLTIN) OXIDE;DTXSID4074485;MUHFQLVFMFDJOK-UHFFFAOYSA-;NSC113258;AKOS025293694;NSC-113258;1,1,1,3,3,3-Hexaphenyldistannoxane #;NS00123590;J-005348

Chemical Property of Bis(triphenyltin) oxide

Chemical Property:

• Appearance/Colour: white crystalline powder and/or crystals
• Vapor Pressure: 0mmHg at 25°C
• Melting Point: 119-123 °C
• Boiling Point: 642.258 °C at 760 mmHg
• Flash Point: 342.226 °C
• PSA: 9.23000
• LogP: 4.33720
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 8
• Exact Mass: 716.03347
• Heavy Atom Count: 39
• Complexity: 551

Purity/Quality:

98%min ^*data from raw suppliers

BIS(TRIPHENYLTIN)OXIDE 98.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): N,T
• Hazard Codes: N-T,N,T
• Statements: 50/53-23/24/25
• Safety Statements: 61-60-45-28A-27-26-28

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[Sn](C2=CC=CC=C2)(C3=CC=CC=C3)O[Sn](C4=CC=CC=C4)(C5=CC=CC=C5)C6=CC=CC=C6
• Uses: Bis(triphenyltin)?oxide is synthesized as an anti-fungal agent and is used in pesticide formulations.

Technology Process of Bis(triphenyltin) oxide

There total 18 articles about Bis(triphenyltin) oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

methanol (67-56-1) + trans-[(Ph3SnO)4Te(OH)2] → trans-[(Ph3SnO)2Te(OMe)4] (1243818-32-7) + bis(triphenyltin) oxide (1262-21-1)

Guidance literature:

In methanol; byproducts: H2O; Sn-Te compd. suspended in MeOH, heated under reflux for several h; filtered, cooled to 4°C; elem. anal.;

DOI:10.1002/zaac.200900376

Reference yield: 38.0%

[n-Bu2NH2][HSeO4]*nH2O + triphenyltin(IV) hydroxide (76-87-9) → [n-Bu2NH2]3[SnPh3(SeO4)2] + bis(triphenyltin) oxide (1262-21-1)

Guidance literature:

In ethanol; at 20 ℃; for 2h;

DOI:10.1515/mgmc-2014-0011

Reference yield:

Ph3Sn(μONNO)SnPh3 (19254-28-5) → bis(triphenyltin) oxide (1262-21-1) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With (η5-C5Me5)Cr(CO)3H; In dichloromethane; at 77.9 ℃; Reagent/catalyst; Solvent; Mechanism; Glovebox; Inert atmosphere;

DOI:10.1021/acs.inorgchem.1c01291

upstream raw materials:

water

triphenyltin chloride

2-Methylbenzothiazole

N-Bromosuccinimide

Downstream raw materials:

triphenyl methyl tin

(C₂H₅)3NCH₃⁽¹⁺⁾*(C₆H₅)3Sn(OSO₂CH₃)2^(1-)=((C₂H₅)3NCH₃)[(C₆H₅)3Sn(OSO₂CH₃)2]

bis(triphenyltin)sulfite

Refernces

• 1、 Diallo, Waly,Diop, Libasse,Plasseraud, Laurent,Cattey, Hlne. "[n-Bu2NH2]3[SnPh3(SeO4)2]: The first triorganotin(IV) complex with terminally coordinated selenato ligands". . p. 107 - 112. Retrieved 2014.
• 2、 Heratrich, Tobias,Merzweiler, Kurt. "Synthesis and properties of Ph3Sn substituted tellurates - The crystal structures of trans-[(Ph3SnO)4Te(OH)2] and trans-[(Ph3SnO)2Te(OMe)4]". . p. 803 - 807. Retrieved 2010/09/04.