Ph3Sn(μONNO)SnPh3

Base Information

• Chemical Name: Ph3Sn(μONNO)SnPh3
• CAS No.: 19254-28-5
• Molecular Formula: C₃₆H₃₀N₂O₂Sn₂
• Molecular Weight: 760.066
• Mol file: 19254-28-5.mol

Synonyms:Ph3Sn(μONNO)SnPh3

Chemical Property of Ph3Sn(μONNO)SnPh3

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of Ph3Sn(μONNO)SnPh3

There total 2 articles about Ph3Sn(μONNO)SnPh3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.1%

silver hyponitrite + triphenyltin chloride (639-58-7) → Ph3Sn(μONNO)SnPh3 (19254-28-5)

Guidance literature:

In dichloromethane; for 2h; Darkness; Inert atmosphere;

DOI:10.1021/acs.inorgchem.1c01291

Reference yield: 37.0%

silver hyponitrite + triphenyltin chloride (639-58-7) → Ph3Sn(μONNO)SnPh3 (19254-28-5)

Guidance literature:

In toluene; byproducts: AgCl; soln. Ph3SnCl (toluene), Ag2N2O2 added; stirred for 20 h under exclusionof light;; filtration of ppt. (AgCl); crystn. (toluene/iso-hexane); elem. anal.;

DOI:10.1002/zaac.201000444

Reference yield:

Ph3Sn(μONNO)SnPh3 (19254-28-5) → bis(triphenyltin) oxide (1262-21-1) + dinitrogen monoxide (10024-97-2)

Guidance literature:

With (η5-C5Me5)Cr(CO)3H; In dichloromethane; at 77.9 ℃; Reagent/catalyst; Solvent; Mechanism; Glovebox; Inert atmosphere;

DOI:10.1021/acs.inorgchem.1c01291

upstream raw materials:

triphenyltin chloride

Downstream raw materials:

bis(triphenyltin) oxide

dinitrogen monoxide

Refernces

• 1、 Captain, Burjor,Davis, Jack V.,Gamage, Mohan M.,Guio, Oswaldo,Hoff, Carl D.,Temprado, Manuel. "Mechanistic Pathways for N2O Elimination from trans-R3Sn-O-N=N-O-SnR3and for Reversible Binding of CO2to R3Sn-O-SnR3(R = Ph, Cy)". supporting information. p. 12075 - 12084. Retrieved 2021/08/24.