Chlorosyl

Base Information

• Chemical Name: Chlorosyl
• CAS No.: 14989-30-1
• Molecular Formula: ClO
• Molecular Weight: 52.4603
• DSSTox Substance ID: DTXSID90924342
• Nikkaji Number: J1.386.188I
• Mol file: 14989-30-1.mol

Synonyms:chlorine oxide (ClO);chlorosyl;chlorosyl ion

Chemical Property of Chlorosyl

Chemical Property:

• XLogP3: 0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 50.9637673
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [O]Cl

Technology Process of Chlorosyl

There total 91 articles about Chlorosyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 2.0%

chlorine dioxide (10049-04-4,25052-55-5) → chlorine dioxide (17376-09-9) + clorine (14700-96-0,14835-24-6,15723-23-6,16547-50-5,16885-04-4,16887-00-6,16904-11-3,16904-12-4,16999-02-3,20337-89-7,20499-73-4,22537-15-1,22537-27-5,22541-73-7,22541-74-8,24203-47-2,33944-49-9,34937-26-3,37352-90-2) + chlorine monoxide (14989-30-1)

Guidance literature:

Irradiation (UV/VIS);

DOI:10.1021/ja002148o

Reference yield:

sodium chlorite (7758-19-2) + water (7732-18-5) + chlorine (7782-50-5) → chlorine dioxide (10049-04-4,25052-55-5) + hypochloric acid (14989-30-1,7790-92-3)

Guidance literature:

With acetic acid-acetate buffer; sodium chloride; In water; react. of Cl2 soln. with aq. soln. of NaClO2 (excess) in presence of acetate buffer (pH 4.2-6.04) at 25°C, ionic strength 1.0 M (NaCl); monitored spectrophotometrically; Kinetics;

DOI:10.1021/ic010762a

Reference yield:

sodium phosphate → sodium dihydrogenphosphate (10049-21-5) + hypochloric acid (14989-30-1,7790-92-3) + sodium chloride (7647-14-5)

Guidance literature:

With chlorine; In not given; soln. of Na3PO4 is treared with Cl2;; heterogeneous product mixture obtained; HClO can be distd.;;

upstream raw materials:

N-chlorodibenzoylamine

water

hydroxyl

nitrosylchloride

Downstream raw materials:

nonan-1-al

sulfuric acid

2-chloro-6-methyl-cyclohexanol

2-(4-chlorobenzoyl)pyrrole

Refernces

• 1、 Remick, A. E.. "". . p. 534 - 545. Retrieved 1942.
• 2、 Abel, Bernd,Hamann, Hilmar H.,Kachanov, Alexander A.,Troe, Juergen. "Intracavity laser absorption spectroscopy of HOCI overtones. I. the 3v1+2v2 band and numbers of vibrational states". . p. 3189 - 3197. Retrieved 1996.
• 3、 Cheng, Bing-Ming,Lee, Yuan-Pern. "Production and trapping of gaseous dimeric ClO: The infrared spectrum of chlorine peroxide (ClOOCl) in solid argon". . p. 5930 - 5935. Retrieved 1989.
• 4、 Soper, F. G.,Smith, G. F.. "". . . Retrieved 1926.
• 5、 Ren, Zhandong,Quan, Shanshan,Gao, Jie,Li, Wenyang,Zhu, Yuchan,Liu, Ye,Chai, Bo,Wang, Yourong. "The electrocatalytic activity of IrO2-Ta2O5 anode materials and electrolyzed oxidizing water preparation and sterilization effect". . p. 8778 - 8786. Retrieved 2015.
• 6、 Berland,Tolbert,George. "Surface sensitive studies of the reactive uptake of chlorine nitrate on ice". . p. 9954 - 9963. Retrieved 1997.
• 7、 Zelenov,Aparina,Kashtanov,Shestakov,Gershenzon. "Kinetic mechanism of ClONO2 uptake on polycrystalline film of NaCl". . p. 6771 - 6780. Retrieved 2006.
• 8、 Connick, R. E.,Chia, Y.-T.. "". . p. 1280 - 1284. Retrieved 1959.
• 9、 Nickolaisen, Scott L.,Roehl, Coleen M.,Blakeley, Lisa K.,Friedl, Randall R.,Francisco, Joseph S.,Liu, Ruifeng,Sander, Stanley P.. "Temperature Dependence of the HO2 + ClO Reaction. 1. Reaction Kinetics by Pulsed Photolysis-Ultraviolet Absorption and ab Initio Studies of the Potential Surface". . p. 308 - 319. Retrieved 2000.
• 10、 Lengyel,Li,Kustin,Epstein. "Rate constants for reactions between iodine- and chlorine-containing species: A detailed mechanism of the chlorine dioxide/chlorite-iodide reaction". . p. 3708 - 3719. Retrieved 1996.