Tetrabutylphosphonium acetate

Base Information

• Chemical Name: Tetrabutylphosphonium acetate
• CAS No.: 30345-49-4
• Molecular Formula: C16H36P^.C2H3O2
• Molecular Weight: 318.48
• Hs Code.: 2931900090
• European Community (EC) Number: 250-139-8
• DSSTox Substance ID: DTXSID20952693
• Mol file: 30345-49-4.mol

Synonyms:Tetrabutylphosphonium acetate;30345-49-4;tetrabutylphosphanium;acetate;EINECS 250-139-8;Phosphonium, tetrabutyl-, acetate (1:1);tetrabutylphosphonium acetate acetic acid salt;C16H36P.C2H4O2.C2H3O2;tetrabutylphosphanium acetate;Phosphonium, tetrabutyl-, acetate, monoacetate;C16-H36-P.C2-H4-O2.C2-H3-O2;SCHEMBL123876;C16H36P.C2H3O2;DTXSID20952693;Phosphonium, tetrabutyl-, acetate;AMY13787;MFCD00050247;AKOS015901805;acetic acid,tetrabutylphosphanium,acetate;C16-H36-P.C2-H3-O2;FT-0759893

Chemical Property of Tetrabutylphosphonium acetate

Chemical Property:

• Appearance/Colour: Colourless to light yellow liquid
• PSA: 53.72000
• LogP: 4.96060
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 318.26876748
• Heavy Atom Count: 21
• Complexity: 142

Purity/Quality:

99.9% ^*data from raw suppliers

TETRABUTYLPHOSPHONIUMACETATE 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[P+](CCCC)(CCCC)CCCC.CC(=O)[O-]

Technology Process of Tetrabutylphosphonium acetate

There total 4 articles about Tetrabutylphosphonium acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.3%

silver(I) acetate (563-63-3) + tetra-n-butylphosphonium chloride (2304-30-5) → tetra-n-butylphosphonium acetate (30345-49-4)

Guidance literature:

In water; isopropyl alcohol; at 20 ℃; for 16h; Inert atmosphere;

DOI:10.1039/c6gc00183a

Reference yield: 95.0%

tetra-n-butylphosphonium hydroxide (14518-69-5) + acetic acid (64-19-7,77671-22-8) → tetra-n-butylphosphonium acetate (30345-49-4)

Guidance literature:

for 0.416667h;

DOI:10.1039/c2cy20760e

Reference yield:

ammonium acetate (631-61-8,92206-38-7) + tetrabutyl phosphonium bromide (3115-68-2) → tetra-n-butylphosphonium acetate (30345-49-4)

Guidance literature:

With Amberlyst A₂₆ hydroxide form;

DOI:10.1039/c2gc35631g

upstream raw materials:

tetra-n-butylphosphonium hydroxide

acetic acid

ammonium acetate

tetrabutyl phosphonium bromide

Downstream raw materials:

acetic acid methyl ester

2-hydroxyethyl acetate

ethylene glycol diacetate

ethylene glycol

Refernces

• 1、 Deb, Somdatta,Labafzadeh, Sara R.,Liimatainen, Unna,Parviainen, Arno,Hauru, Lauri K. J.,Azhar, Shoaib,Lawoko, Martin,Kulomaa, Tuomas,Kakko, Tia,Fiskari, Juha,Borrega, Marc,Sixta, Herbert,Kilpel?inen, Ilkka,King, Alistair W. T.. "Application of mild autohydrolysis to facilitate the dissolution of wood chips in direct-dissolution solvents". . p. 3286 - 3294. Retrieved 2016.
• 2、 Qu, Xiaoling,Zhou, Guangyuan,Wang, Rui,Yuan, Bolei,Jiang, Min,Tang, Jun. "Synergistic catalysis of imidazole acetate ionic liquids for the methanolysis of spiral poly(ethylene 2,5-furandicarboxylate) under a mild condition". . p. 1871 - 1882. Retrieved 2021/03/09.