Nonaborane(9),nonachloro- (9CI)

Base Information

• Chemical Name: Nonaborane(9),nonachloro- (9CI)
• CAS No.: 12008-47-8
• Molecular Formula: B9Cl9
• Molecular Weight: 416.376
• Mol file: 12008-47-8.mol

Synonyms:Boronchloride (B9Cl9) (8CI); Nonachlorononaborane; Nonachlorononaboron

Chemical Property of Nonaborane(9),nonachloro- (9CI)

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Nonaborane(9),nonachloro- (9CI)

There total 7 articles about Nonaborane(9),nonachloro- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

trichlorofluoromethane (75-69-4) + diboron tetrachloride (13701-67-2) → nonachlorononaborane(9) (12008-47-8) + B10Cl10 (61674-49-5) + B8Cl8 (32915-80-3) + diboron tetrafluoride (13965-73-6)

Guidance literature:

In trichlorofluoromethane; byproducts: CCl4; B2Cl4 and 10-fold excess CCl3F were heated in a sealed tube at 90°C for 61 h; partially septd. by fractionation at -95 to -160°C; products detected by (19)F- and (11)B-NMR, CCl4 by (13)C-NMR;

Reference yield:

B10F12 + boron trichloride (10294-34-5) → nonachlorononaborane(9) (12008-47-8) + boron trifluoride (7637-07-2) + boron difluoridechloride (14720-31-1) + boron fluoridedichloride (14720-30-0)

Guidance literature:

In dichloromethane-d2; B salts mixed at o°C, warmed to 60°C, extd.(CD2Cl2); NMR;

DOI:10.1016/S0277-5387(01)01032-4

Reference yield:

B8F12 + boron trichloride (10294-34-5) → nonachlorononaborane(9) (12008-47-8) + boron trifluoride (7637-07-2) + boron difluoridechloride (14720-31-1) + boron fluoridedichloride (14720-30-0)

Guidance literature:

In dichloromethane-d2; B salts mixed at o°C, warmed to 60°C, extd.(CD2Cl2); NMR;

DOI:10.1016/S0277-5387(01)01032-4

upstream raw materials:

boron trichloride

trichlorofluoromethane

diboron tetrachloride

Refernces

• 1、 Saulys,Castillo,Morrison. "Fluorination of boron chlorides and boron bromides by reaction with bis(trifluoromethyl)mercury, trichlorofluoromethane, or tribromofluoromethane: Synthesis of BF2B5H8". . p. 1619 - 1624. Retrieved 2008/10/08.
• 2、 Davan,Morrison. "2n framework electron clusters: Diamagnetic polyhedral boron chlorides, BnCln (n = 8-12), from the thermal disproportionation of diboron tetrachloride". . p. 2366 - 2372. Retrieved 2008/10/08.