Technology Process of Bis(trimethylsilyl)mercury
There total 4 articles about Bis(trimethylsilyl)mercury which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
lithium; sodium iodide; sodium chloride;
In
diethyl ether;
byproducts: LiCl; under Ar and exclusion of O2 and moisture, a mixt. of Li, NaCl, NaI and Hg in Et2O is stirred for 3 h, then addn. of Me3SiCl in Et2O and stirred for 3 d; evapn. of the soln. (vac., room temp.), residue is washed with pentane, removal of pentane (vac., room temp.);
- Guidance literature:
-
In
diethyl ether;
mixt. of amalgam and Me3SiCl was mechanically stirred in slurry of NaCl,NaI and Et2O for 3 d in the dark; according to Rosch, L., Altnau, G., H ahn, E., Havemann, H. Z. Naturforsch, 1981, 36b, 1234; mixt. was extd. in pentane and sublimed under high vac.;
DOI:10.1021/om0201720
- Guidance literature:
-
sublimation (vac., 60°C);
