Chlorine nitrite

Base Information

• Chemical Name: Chlorine nitrite
• CAS No.: 65283-98-9
• Molecular Formula: ClNO₂
• Molecular Weight: 81.4585
• Mol file: 65283-98-9.mol

Synonyms:Chlorine nitrite

Chemical Property of Chlorine nitrite

Chemical Property:

• XLogP3: 0.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 80.9617559
• Heavy Atom Count: 4
• Complexity: 20

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: N(=O)OCl

Technology Process of Chlorine nitrite

There total 7 articles about Chlorine nitrite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trichlorosilane (10025-78-2) + oxygen (80937-33-3) + chlorine (7782-50-5) + Nitrogen dioxide (10102-44-0) → tetrachlorosilane (10026-04-7,53609-55-5) + SiCl3ONO2 (97190-54-0) + SiCl3O2NO2 (97190-53-9) + chloronitrite (65283-98-9) + Nitryl chloride (13444-90-1)

Guidance literature:

In gas; Irradiation (UV/VIS); on photolysis (>= 300nm);; not isolated, monitoring of react. by IR (assignment proved by (15)N-labeling);;

DOI:10.1021/j100263a028

Reference yield:

oxygen (80937-33-3) + Nitryl chloride (13444-90-1) → chlorine nitrate (14545-72-3) + cis-chlorine nitrile (65283-98-9) + trans-ONOCl (65283-98-9) + ozone (10028-15-6) + nitrosylchloride (2696-92-6)

Guidance literature:

In solid matrix; byproducts: O3*O; Irradiation (UV/VIS); photolysis at 266 nm for 120 min in solid O2; not isolated, detected by IR;

DOI:10.1016/S0301-0104(01)00607-3

Reference yield:

oxygen (80937-33-3) + Nitryl chloride (13444-90-1) → chlorine nitrate (14545-72-3) + cis-chlorine nitrile (65283-98-9) + trans-ONOCl (65283-98-9) + ozone (10028-15-6) + nitrosylchloride (2696-92-6)

Guidance literature:

In solid matrix; byproducts: O3*O; Irradiation (UV/VIS); photolysis at 266 nm for 120 min in solid O2; not isolated, detected by IR;

DOI:10.1016/S0301-0104(01)00607-3

upstream raw materials:

trichlorosilane

oxygen

chlorine

Nitrogen dioxide

Refernces

• 1、 Sodeau, John R.,Roddis, Tristan B.,Gane, Matt P.. "A study of the heterogeneous reaction between dinitrogen pentaoxide and chloride ions on low-temperature thin films". . p. 1890 - 1897. Retrieved 2007/10/03.
• 2、 Niki, H.,Maker, P. D.,Savage, C. M.,Breitenbach, L. P.,Hurley, M. D.. "FTIR Study of the Kinetics and Mechanism for the Cl-Atom-Initiated Reactions of SiHCl3". . p. 3725 - 3729. Retrieved 2007/10/02.