Chlorine nitrate

Base Information

• Chemical Name: Chlorine nitrate
• CAS No.: 14545-72-3
• Molecular Formula: ClN O3
• Molecular Weight: 97.4579
• DSSTox Substance ID: DTXSID00163043
• Wikipedia: Chlorine_nitrate
• Wikidata: Q2563692
• Mol file: 14545-72-3.mol

Synonyms:Chlorine nitrate;chloro nitrate;14545-72-3;Nitric acid chlorine salt;Nitryl hypochlorite ((NO2)(OCl));Chlornitrat;ClONO2;ClNO3;Cl-N-O3;DTXSID00163043;Nitryl hypochlorite ((NO2)(ClO));Q2563692

Chemical Property of Chlorine nitrate

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 55.05000
• Density: 1.65g/cm³
• LogP: 0.87170
• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 0
• Exact Mass: 96.9566706
• Heavy Atom Count: 5
• Complexity: 36.6

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [N+](=O)([O-])OCl

Technology Process of Chlorine nitrate

There total 5 articles about Chlorine nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

sodium nitrate (7631-99-4) + chlorine monofluoride (7790-89-8) → hypochlorous anhydride (7791-21-1) + chlorine nitrate (14545-72-3) + nitrylfluoride (10022-50-1)

Guidance literature:

In neat (no solvent); byproducts: NaF; mixt. of NaNO3 (excess) and ClF in a stainless steel cylinder allowed to warm slowly in a dry-ice-liquid N2 slush bath from -196°VC to -78 and then toward 0°C, recooled to -196°C; fractional condensation;

Reference yield: 60.0%

sodium nitrate (7631-99-4) + chlorine monofluoride (7790-89-8) → hypochlorous anhydride (7791-21-1) + chlorine nitrate (14545-72-3) + FClO2 (13637-83-7)

Guidance literature:

In neat (no solvent); byproducts: Cl2, NaF; finely powdered NaNO3 loaded into a stainless steeel cylinder, ClF (excess) added at -196°C, cylinder allowed to warm slowly to room temp., kept for 3d, cooled to -196°C; fractional condensation;

Reference yield:

oxygen (80937-33-3) + Nitryl chloride (13444-90-1) → chlorine nitrate (14545-72-3) + cis-chlorine nitrile (65283-98-9) + trans-ONOCl (65283-98-9) + ozone (10028-15-6) + nitrosylchloride (2696-92-6)

Guidance literature:

In solid matrix; byproducts: O3*O; Irradiation (UV/VIS); photolysis at 266 nm for 120 min in solid O2; not isolated, detected by IR;

DOI:10.1016/S0301-0104(01)00607-3

upstream raw materials:

oxygen

Nitryl chloride

chloropicrin

sodium nitrate

Downstream raw materials:

chlorine

dinitrogen tetraoxide

hydrogenchloride

sodium nitrate

Refernces

• 1、 Hatakeyama, Shiro,Imamura, Takashi,Washida, Nobuaki. "Enhanced formation of ozone by the addition of chloropicrin (trichloronitromethane) to propene/NO/air/photoirradiation systems". . p. 1497 - 1500. Retrieved 2007/10/03.