1,4-Dioxan-2-yl

Base Information

• Chemical Name: 1,4-Dioxan-2-yl
• CAS No.: 4598-47-4
• Molecular Formula: C4H7 O2
• Molecular Weight: 87.0984
• Mol file: 4598-47-4.mol

Synonyms:p-Dioxan-2-yl(7CI,8CI); 1,4-Dioxanyl

Chemical Property of 1,4-Dioxan-2-yl

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,4-Dioxan-2-yl

There total 6 articles about 1,4-Dioxan-2-yl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,4-dioxane (123-91-1,28347-88-8,28347-91-3,39449-24-6,54841-74-6) → dioxanyl radical (4598-47-4)

Guidance literature:

With di-tert-butyl peroxide; In various solvent(s); at -60 ℃; Irradiation; relative rate of hydrogen abstraction toward tert-butoxyl; stereoelectronic effects in this process was compared for a series of cyclic and acyclic ethers (for THF relative and absolute reactivities was determined);

DOI:10.1021/ja00393a018

Reference yield:

1,4-dioxane (123-91-1,28347-88-8,28347-91-3,39449-24-6,54841-74-6) → dioxanyl radical (4598-47-4) + C4H7O(1+) (78386-43-3,1253600-56-4)

Guidance literature:

With sodium persulfate; at 80 ℃;

DOI:10.1039/c4cc06864e

Reference yield:

1,4-dioxane (123-91-1,28347-88-8,28347-91-3,39449-24-6,54841-74-6) + benzophenone (119-61-9) → dioxanyl radical (4598-47-4) + hydroxy-diphenyl-methyl (4971-41-9)

Guidance literature:

laser flash photolysis;

DOI:10.1021/ja0647405

upstream raw materials:

1,4-dioxane

tert-butoxy radical

Dikaliumsalz von Acetylendicarbonsaeure

benzophenone

Downstream raw materials:

1,4-dioxane-2-ol

1,4-dioxane

Penicillamine thiyl radical

Refernces

• 1、 Huie, Robert E.,Clifton, Carol L.,Kafafi, Sherif A.. "Rate Constants for Hydrogen Abstraction Reactions of the Sulfate Radical, SO4(1-). Experimental and Theoretical Results for Cyclic Ethers". . p. 9336 - 9340. Retrieved 1991.
• 2、 Lunazzi, Lodovico,Placucci, Giuseppe,Grossi, Loris. "REACTIONS OF ALKANETHIYL AND ALKOXYL RADICALS WITH UNSATURATED CYCLIC ETHERS". . p. 159 - 163. Retrieved 1983.
• 3、 Seth, Kapileswar,Nautiyal, Manesh,Purohit, Priyank,Parikh, Naisargee,Chakraborti, Asit K.. "Palladium catalyzed Csp2-H activation for direct aryl hydroxylation: The unprecedented role of 1,4-dioxane as a source of hydroxyl radicals". supporting information. p. 191 - 194. Retrieved 2015/01/09.