Silane, bis(4-butylphenyl)dichloro-

Base Information

• Chemical Name: Silane, bis(4-butylphenyl)dichloro-
• CAS No.: 111939-57-2
• Molecular Formula: C20H26Cl2Si
• Molecular Weight: 365.418
• DSSTox Substance ID: DTXSID60400643
• Nikkaji Number: J1.077.968E
• Wikidata: Q82203649
• Mol file: 111939-57-2.mol

Synonyms:bis(4-butylphenyl)dichlorosilane;Silane, bis(4-butylphenyl)dichloro-;111939-57-2;SCHEMBL686713;DTXSID60400643;DNVXMKXNGVYVRL-UHFFFAOYSA-N

Chemical Property of Silane, bis(4-butylphenyl)dichloro-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 8
• Exact Mass: 364.1180828
• Heavy Atom Count: 23
• Complexity: 286

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC1=CC=C(C=C1)[Si](C2=CC=C(C=C2)CCCC)(Cl)Cl

Technology Process of Silane, bis(4-butylphenyl)dichloro-

There total 2 articles about Silane, bis(4-butylphenyl)dichloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

tetrachlorosilane (10026-04-7,53609-55-5) + p-bromobutylbenzene (41492-05-1) → dichloro-di(4-n-butylphenyl)silane (111939-57-2)

Guidance literature:

p-bromobutylbenzene; With ethyl bromide; magnesium; In tetrahydrofuran; Heating / reflux;

tetrachlorosilane; In tetrahydrofuran; n-heptane; for 2h; Heating / reflux;

Reference yield: 38.0%

p-bromobutylbenzene (41492-05-1) → dichloro-di(4-n-butylphenyl)silane (111939-57-2)

Guidance literature:

p-bromobutylbenzene; With magnesium; In tetrahydrofuran; diethyl ether; Inert atmosphere; Reflux;

With tetrachlorosilane; In tetrahydrofuran; diethyl ether; at 0 ℃; for 4h; Inert atmosphere;

DOI:10.1080/10426507.2015.1049744

Reference yield: 11.0%

dichloro-di(4-n-butylphenyl)silane (111939-57-2) → poly[bis(p-butylphenyl)silane]

Guidance literature:

With lithium aluminium tetrahydride; In diethyl ether; at 0 - 20 ℃; for 1h; Schlenk technique; Inert atmosphere;

DOI:10.1080/10426507.2015.1094657

upstream raw materials:

tetrachlorosilane

p-bromobutylbenzene

Refernces

• 1、 Binder, Judith,Fischer, Roland C.,Flock, Michaela,Torvisco, Ana,Uhlig, Frank. "Novel Aryl Substituted Silanes Part I: Synthesis and Characterization of Diaryl Silicon Dichlorides". . p. 1980 - 1994. Retrieved 2015/12/12.