Carbamodithioic acid, diethyl-, 2-(hydroxyimino)-2-phenylethyl ester, (Z)-

Base Information

• Chemical Name: Carbamodithioic acid, diethyl-, 2-(hydroxyimino)-2-phenylethyl ester, (Z)-
• CAS No.: 112051-07-7
• Molecular Formula: C₁₃H₁₈N₂OS₂
• Molecular Weight: 282.431
• Mol file: 112051-07-7.mol

Synonyms:

Chemical Property of Carbamodithioic acid, diethyl-, 2-(hydroxyimino)-2-phenylethyl ester, (Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbamodithioic acid, diethyl-, 2-(hydroxyimino)-2-phenylethyl ester, (Z)-

There total 2 articles about Carbamodithioic acid, diethyl-, 2-(hydroxyimino)-2-phenylethyl ester, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

2-chloro-1-phenyl-ethanone oxime (21572-32-7) + diethylammonium diethyldithiocarbamate (1518-58-7) → Diethyl-dithiocarbamic acid 2-[(E)-hydroxyimino]-2-phenyl-ethyl ester (112051-07-7,112051-08-8)

Guidance literature:

In ethanol; for 18h; Ambient temperature;

DOI:10.1055/s-1987-27940

Reference yield:

2-chloro-1-phenyl-ethanone oxime (21572-32-7) + diethylammonium diethyldithiocarbamate (1518-58-7) → Diethyl-dithiocarbamic acid 2-[(E)-hydroxyimino]-2-phenyl-ethyl ester (112051-08-8) + Diethyl-dithiocarbamic acid 2-[(Z)-hydroxyimino]-2-phenyl-ethyl ester (112051-07-7)

Guidance literature:

In ethanol; for 18h; Yield given. Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1055/s-1987-27940

Reference yield: 38.0%

Diethyl-dithiocarbamic acid 2-[(E)-hydroxyimino]-2-phenyl-ethyl ester (112051-07-7,112051-08-8) → C26H30N4S4 (112051-23-7)

Guidance literature:

With Tosyl isocyanate; In benzene; for 24h; Heating;

DOI:10.1055/s-1987-27940

upstream raw materials:

2-chloro-1-phenyl-ethanone oxime

diethylammonium diethyldithiocarbamate

Downstream raw materials:

C₂₆H₃₀N₄S₄

Refernces