Trichloro(3,3,3-trifluoropropyl)silane

Base Information

• Chemical Name: Trichloro(3,3,3-trifluoropropyl)silane
• CAS No.: 592-09-6
• Molecular Formula: C3H4Cl3F3Si
• Molecular Weight: 231.504
• Hs Code.: 2931900090
• European Community (EC) Number: 209-744-2
• UNII: A2MIV9WA9Z
• DSSTox Substance ID: DTXSID8060458
• Nikkaji Number: J188.465D
• Wikidata: Q72510476
• Mol file: 592-09-6.mol

Synonyms:3,3,3-TFPTClSi;3,3,3-trifluoropropyltrichlorosilane

Chemical Property of Trichloro(3,3,3-trifluoropropyl)silane

Chemical Property:

• Appearance/Colour: Colorless clear liquid
• Vapor Pressure: 62.7mmHg at 25°C
• Refractive Index: n20/D 1.386(lit.)
• Boiling Point: 90.8 °C at 760 mmHg
• Flash Point: 8.7 °C
• PSA: 0.00000
• Density: 1.408 g/cm³
• LogP: 3.59410
• Sensitive.: Moisture Sensitive
• Water Solubility.: Reacts with water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 1
• Exact Mass: 229.909994
• Heavy Atom Count: 10
• Complexity: 107

Purity/Quality:

98%,99%, ^*data from raw suppliers

(3,3,3-Trifluoropropyl)trichlorosilane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C
• Hazard Codes: F,C
• Statements: 11-14-34
• Safety Statements: 16-26-27-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C(C[Si](Cl)(Cl)Cl)C(F)(F)F
• Uses: (3,3,3-Trifluoropropyl)trichlorosilane is used for the production of fluoro silicones liquids. Trichloro(3,3,3-trifluoropropyl)silane can be used as a precursor for the preparation of: Fluorinated polyhedral oligomeric silsesquioxane (F-POSS) by base-catalyzed condensation.???????? 3,3,3-Trifluoropropyltrimethoxysilane by alcoholysis reaction with methanol.It can also be used as a silanizing agent to coat the inner surface of pipettes in order to investigate the electrical charging of droplets discharged from the micropipette.

Technology Process of Trichloro(3,3,3-trifluoropropyl)silane

There total 13 articles about Trichloro(3,3,3-trifluoropropyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

→ 3,3,3-trifluoropropyltrichlorosilane (592-09-6)

Guidance literature:

Reference yield: 75.0%

1,1,1-trifluoropropylene (677-21-4) → 3,3,3-trifluoropropyltrichlorosilane (592-09-6)

Guidance literature:

With trichlorosilane; RhCl(PPh₃)3; at 120 ℃; for 36h;

DOI:10.1016/S0022-328X(00)99483-X

Reference yield:

2,3,3,3-tetrafluoro-propene (754-12-1) → 3,3,3-trifluoropropyltrichlorosilane (592-09-6)

Guidance literature:

With Wilkinson's catalyst; trichlorosilane; In neat (no solvent); at 120 ℃; for 24h;

DOI:10.1002/ejoc.202000853

upstream raw materials:

1,1,1-trifluoropropylene

3,3,3-trifluoropriopylsilane

(2-Chlor-aethyl)-dichlor-(3,3,3-trifluor-propyl)-silan

2,3,3,3-tetrafluoro-propene

Downstream raw materials:

3,3,3-trifluoropropyltrimethoxysilane

chlorodimethyl-3,3,3-trifluoropropylsilane

octamethylsilsesquioxane

Refernces

• 1、 -. "PROCESS FOR PREPARING ORGANOCHLOROSILANES BY DEHYDROHALOGENATIVE COUPLING REACTION OF ALKYL HALIDES WITH CHLOROSILANES". . . Retrieved 2008/06/13.
• 2、 -. "Dehydrohalogenative coupling reaction of organic halides with silanes". . . Retrieved 2008/06/13.