Tetraethylammonium cyanide

Base Information

• Chemical Name: Tetraethylammonium cyanide
• CAS No.: 13435-20-6
• Molecular Formula: C8 H20 N
• Molecular Weight: 156.271
• Hs Code.: 2926909090
• European Community (EC) Number: 236-566-2
• DSSTox Substance ID: DTXSID70158668
• Wikipedia: Tetraethylammonium cyanide,Tetraethylammonium_cyanide
• Wikidata: Q83026984
• Mol file: 13435-20-6.mol

Synonyms:Tetraethylammonium cyanide;13435-20-6;tetraethylazanium;cyanide;Ethanaminium,N,N,N-triethyl-, hydrocyanic acid (1:1);Ethanaminium, N,N,N-triethyl-, cyanide;EINECS 236-566-2;Tetraethylammoniumcyanide;tetraethyl ammonium cyanide;C8H20N.CN;SCHEMBL152478;DTXSID70158668;C8-H20-N.C-N;PCZOZSATUTWXIC-UHFFFAOYSA-N;STR07566;AKOS028108730;F14815;TRANS,TRANS-3,4,5-TRIFLUOROPHENYL4-PENTYLBICYCLOHEXYL-4-CARBOXYLATE

Chemical Property of Tetraethylammonium cyanide

Chemical Property:

• Melting Point: 250 °C (dec.)(lit.)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 23.79000
• Density: g/cm³
• LogP: 1.97918
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 4
• Exact Mass: 156.162648646
• Heavy Atom Count: 11
• Complexity: 57.5

Purity/Quality:

98%,99%, ^*data from raw suppliers

Tetraethylammonium cyanide ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T+,N
• Statements: 26/27/28-32-50/53
• Safety Statements: 7-28-29-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC[N+](CC)(CC)CC.[C-]#N
• Uses: Tetraethylammonium cyanide is a versatile reagent commonly used in cyanation reactions as cyanide source. It is also used in the preparation of various cyanometalate complexes.

Technology Process of Tetraethylammonium cyanide

There total 3 articles about Tetraethylammonium cyanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

potassium cyanide + tetraethylammonium chloride (56-34-8) → tetraethylammoniumcyanide (13435-20-6)

Guidance literature:

In water; for 1h; Reflux;

DOI:10.1021/acs.cgd.6b01819

Reference yield: 50.6%

tetraethylammonium chloride (56-34-8) → tetraethylammoniumcyanide (13435-20-6)

Guidance literature:

In methanol;

DOI:10.1016/0022-328X(87)80326-1

Reference yield:

→ tetraethylammoniumcyanide (13435-20-6)

Guidance literature:

DOI:10.1021/ja00878a017

upstream raw materials:

tetraethylammonium chloride

Downstream raw materials:

2-cyano-2-methyl-propionic acid ethyl ester

cyclopentanecarbonitrile

2,2-dimethyl-3-oxobutanenitrile

cyanoacetic acid tert-butyl ester

Refernces

• 1、 Rosenblum, Myron,Turnbull, Mark M.,Begum, M.Kohinoor. "η2-Acrylonitrilecyclopentadienyldicarbonyliron(II) tetrafluoroborate: an Unusual High-valent Transition Metal Complex". . p. 67 - 78. Retrieved 1987.