9,10-BIS(4-METHOXYPHENYL)ANTHRACENE

Base Information

• Chemical Name: 9,10-BIS(4-METHOXYPHENYL)ANTHRACENE
• CAS No.: 24672-76-2
• Molecular Formula: C28H22O2
• Molecular Weight: 390.481
• Hs Code.: 2909309090
• Mol file: 24672-76-2.mol

Synonyms:Anthracene,9,10-bis(p-methoxyphenyl)- (6CI,7CI,8CI);9,10-Bis(4-methoxyphenyl)anthracene;9,10-Bis(p-anisyl)anthracene;9,10-Bis-p-methoxyphenyl-anthracene;9,10-Di(p-methoxyphenyl)anthracene;9,10-Di-p-anisylanthracene;NSC 652541;

Chemical Property of 9,10-BIS(4-METHOXYPHENYL)ANTHRACENE

Chemical Property:

• Vapor Pressure: 1.17E-10mmHg at 25°C
• Melting Point: 274 ºC
• Refractive Index: 1.662
• Boiling Point: 526.8 °C at 760 mmHg
• Flash Point: 190.2 °C
• PSA: 18.46000
• Density: 1.161 g/cm³
• LogP: 7.34420

Purity/Quality:

98%,99%, ^*data from raw suppliers

9,10-Bis(4-methoxyphenyl)anthracene >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9,10-BIS(4-METHOXYPHENYL)ANTHRACENE

There total 22 articles about 9,10-BIS(4-METHOXYPHENYL)ANTHRACENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

9,10-Dibromoanthracene (523-27-3) + 4-methoxyphenylboronic acid (5720-07-0) → 9,10-bis-(4-methoxy-phenyl)-anthracene (24672-76-2)

Guidance literature:

With water; palladium diacetate; cesium fluoride; cyclo-octa-1,5-diene; DavePhos; In neat (no solvent); for 1.65h; Milling; Green chemistry;

DOI:10.1039/c9sc02185j

Reference yield: 94.0%

9,10-bis(4-methoxyphenyl)-9,10-dihydroanthracene-9,10-bis(ylium)bis(trifluoromethanesulfonate) + N,N-diethyl-3,5-dimethylaniline (3995-39-9) → 9,10-bis-(4-methoxy-phenyl)-anthracene (24672-76-2) + N,N,N',N'-tetraethyl-2,2',6,6'-tetramethylbiphenyl-4,4'-diamine

Guidance literature:

at 0 ℃; for 1h;

DOI:10.1002/asia.201300710

Reference yield: 92.0%

9,10-dichloroanthracene (605-48-1) + 4-methoxyphenylboronic acid (5720-07-0) → 9,10-bis-(4-methoxy-phenyl)-anthracene (24672-76-2)

Guidance literature:

With water; palladium diacetate; cesium fluoride; cyclo-octa-1,5-diene; DavePhos; In neat (no solvent); for 1.65h; Milling; Green chemistry;

DOI:10.1039/c9sc02185j

upstream raw materials:

anthracene

para-methoxyphenyldiazonium chloride

9,10-dihydroanthracene-9,10-bis(4-methoxyphenyl)-9,10-diol

9-(p-methoxyphenyl)anthracene

Downstream raw materials:

9,10-bis(4-methoxyphenyl)-9,10-dihydro-9,10-epidioxidoanthracene

9,10-dihydroanthracene-9,10-bis(4-methoxyphenyl)-9,10-diol

9-(4-methoxyphenyl)-10-(4-hydroxyphenyl)anthracene

9,10-bis(4-bromopropoxyphenyl)anthracene

Refernces

• 1、 Sun, Cai-Li,Peng, Hui-Qing,Niu, Li-Ya,Chen, Yu-Zhe,Wu, Li-Zhu,Tung, Chen-Ho,Yang, Qing-Zheng. "Artificial light-harvesting supramolecular polymeric nanoparticles formed by pillar[5]arene-based host-guest interaction". supporting information. p. 1117 - 1120. Retrieved 2018/02/07.
• 2、 Altinok, Esra,Frausto, Fanny,Thomas, Samuel W.. "Water-soluble fluorescent polymers that respond to singlet oxygen". . p. 2526 - 2535. Retrieved 2016/07/14.