9,10-Dichloroanthracene

Base Information

• Chemical Name: 9,10-Dichloroanthracene
• CAS No.: 605-48-1
• Molecular Formula: C14H8Cl2
• Molecular Weight: 247.124
• Hs Code.: 2903999090
• European Community (EC) Number: 210-087-9
• NSC Number: 42963
• DSSTox Substance ID: DTXSID2060541
• Nikkaji Number: J79.715D
• Wikidata: Q81989122
• Mol file: 605-48-1.mol

Synonyms:9,10-DICHLOROANTHRACENE;605-48-1;Anthracene, 9,10-dichloro-;EINECS 210-087-9;NSC 42963;NSC42963;Anthracene,10-dichloro-;9,10-dichloro-anthracene;SCHEMBL147819;DTXSID2060541;MFCD00001246;NSC-42963;STK265437;AKOS005424656;AS-47969;D0327;FT-0621595;F17152

Chemical Property of 9,10-Dichloroanthracene

Chemical Property:

• Appearance/Colour: yellow crystalline powder or chunks
• Vapor Pressure: 2.77E-06mmHg at 25°C
• Melting Point: 210-216 °C
• Refractive Index: 1.72
• Boiling Point: 401.3 °C at 760 mmHg
• Flash Point: 204.9 °C
• PSA: 0.00000
• Density: 1.361 g/cm³
• LogP: 5.29980
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform (Slightly), Dichloromethane (Slightly)
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 246.0003056
• Heavy Atom Count: 16
• Complexity: 203

Purity/Quality:

98% ^*data from raw suppliers

9,10-Dichloroanthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-36
• Safety Statements: 37/39-26-36

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Halogenated Polyaromatics
• Canonical SMILES: C1=CC=C2C(=C1)C(=C3C=CC=CC3=C2Cl)Cl

Technology Process of 9,10-Dichloroanthracene

There total 53 articles about 9,10-Dichloroanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

anthracene (120-12-7) → 9,10-dichloroanthracene (605-48-1)

Guidance literature:

With aluminum oxide; copper dichloride; In tetrachloromethane; at 80 ℃; for 7h;

DOI:10.1021/jo00244a046

Reference yield: 96.0%

anthracene (120-12-7) + cyclohexylamine (108-91-8,157973-60-9) → 9,10-dichloroanthracene (605-48-1) + cyclohexylamine hydrochloride (4998-76-9)

Guidance literature:

With chloroform; oxygen; sodium hydrogencarbonate; triethylamine; In methanol; water; for 1.5h; Irradiation;

DOI:10.1021/ol301356r

Reference yield: 93.0%

9-(tetrachlorophosphoranyloxy)anthracene → 9,10-dichloroanthracene (605-48-1)

Guidance literature:

With phosphorus pentachloride; In benzene; Heating;

upstream raw materials:

9-chloroanthracene

anthracene

anthracen-9(10H)-one

9-benzylanthracene

Downstream raw materials:

9,10-phenanthrenequinone

9-chloroanthracene

anthracene

2,7-diaminoanthraquinone

Refernces

• 1、 Kuwano,Kondo. "". . p. 2779. Retrieved 1966.
• 2、 Nishii, Yuji,Ikeda, Mitsuhiro,Hayashi, Yoshihiro,Kawauchi, Susumu,Miura, Masahiro. "Triptycenyl Sulfide: A Practical and Active Catalyst for Electrophilic Aromatic Halogenation Using N-Halosuccinimides". supporting information. p. 1621 - 1629. Retrieved 2020/02/04.
• 3、 Samanta, Ramesh C.,Yamamoto, Hisashi. "Selective Halogenation Using an Aniline Catalyst". supporting information. p. 11976 - 11979. Retrieved 2015/08/18.