N-Isobutylideneisobutylamine

Base Information

• Chemical Name: N-Isobutylideneisobutylamine
• CAS No.: 6898-82-4
• Molecular Formula: C8H17 N
• Molecular Weight: 127.23
• Hs Code.: 2921199090
• European Community (EC) Number: 230-003-4
• DSSTox Substance ID: DTXSID001246338
• Nikkaji Number: J26.148C
• Mol file: 6898-82-4.mol

Synonyms:N-Isobutylideneisobutylamine;6898-82-4;1-Propanamine, 2-methyl-N-(2-methylpropylidene)-;1-Propanamine,2-methyl-N-(2-methylpropylidene)-;EINECS 230-003-4;Propylamine, N-isobutylidene-2-methyl-;2-methyl-N-(2-methylpropyl)propan-1-imine;N-i-butylidene-i-butylamine;N-isobutylidene-isobutylamine;N-Isobutylidene isobutylamine;isobutylidene -- isobutylamine;N-Isobutylidene-N-isobutylamine;SCHEMBL4089753;SCHEMBL16156656;DTXSID001246338;N-Isobutyl-2-methyl-1-propanimine;2-Methyl-N-(2-methylpropylidene)-1-propanamine;2-Methyl-N-[(E)-2-methylpropylidene]-1-propanamine;2-Methyl-N-[(E)-2-methylpropylidene]-1-propanamine #

Chemical Property of N-Isobutylideneisobutylamine

Chemical Property:

• Vapor Pressure: 1.98mmHg at 25°C
• Boiling Point: 170.1°C at 760 mmHg
• Flash Point: 47.9°C
• PSA: 12.36000
• Density: 0.78g/cm³
• LogP: 2.36920
• XLogP3: 2.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 127.136099547
• Heavy Atom Count: 9
• Complexity: 82.6

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)CN=CC(C)C

Technology Process of N-Isobutylideneisobutylamine

There total 20 articles about N-Isobutylideneisobutylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Isobutyronitrile (78-82-0) → diisobutylamine (110-96-3) + N-isobutylideneisobutylamine (6898-82-4)

Guidance literature:

With hydrogen; at 220 ℃;

DOI:10.1134/S1070427217110088

Reference yield: 80.0%

diisobutylamine (110-96-3) → N-isobutylideneisobutylamine (6898-82-4)

Guidance literature:

With oxygen; In para-xylene; at 130 ℃; for 4h;

DOI:10.1039/c4cc00024b

Reference yield: 77.0%

isobutylamine (78-81-9) → Isobutyronitrile (78-82-0) + N-isobutylideneisobutylamine (6898-82-4)

Guidance literature:

With oxygen; In para-xylene; at 110 ℃; for 2h;

DOI:10.1039/c4cc00024b

upstream raw materials:

chloro-diisobutyl-amine

sodium ethanolate

isobutylamine

isobutyraldehyde

Downstream raw materials:

2-bromo-2-methylpropanal

hydrogen bromide

isobutylamine

4-methyl-1-phenylpentan-1-one

Refernces

• 1、 Chakraborty, Subrata,Milstein, David. "Selective Hydrogenation of Nitriles to Secondary Imines Catalyzed by an Iron Pincer Complex". . p. 3968 - 3972. Retrieved 2017/06/19.
• 2、 Popov, Yu. V.,Mokhov,Latyshova,Nebykov,Panov,Pletneva, M. Yu.. "Colloid and nanosized catalysts in organic synthesis: XVI.1 Continuous hydrogenation of carbonitriles catalyzed by nickel nanoparticles applied on a support". . p. 2276 - 2281. Retrieved 2017/11/24.