Tetrafluoroaluminate Ion

Base Information

• Chemical Name: Tetrafluoroaluminate Ion
• CAS No.: 21340-02-3
• Molecular Formula: AlF₄
• Molecular Weight: 102.975
• Wikidata: Q27095229
• Mol file: 21340-02-3.mol

Synonyms:Al-F4;AlF4 ion;AlF4-;aluminum tetrafluoride;tetrafluoroaluminate

Chemical Property of Tetrafluoroaluminate Ion

Chemical Property:

• PSA: 0.00000
• LogP: -11.64650
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 102.9751511
• Heavy Atom Count: 5
• Complexity: 19.1

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: F[Al-](F)(F)F

Technology Process of Tetrafluoroaluminate Ion

There total 6 articles about Tetrafluoroaluminate Ion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

aluminium(III) ion (22537-23-1) + fluoride (16984-48-8) + adenosine 5'-diphosphate (58-64-0,905904-58-7) → tetrafluoroaluminate(1-) (21340-02-3) + aluminum(III) fluoride (7784-18-1) + {Al(ADP)}

Guidance literature:

In water; below pH 6.4;

DOI:10.1016/S0020-1693(00)90812-0

Reference yield:

fluorine (7782-41-4) + aluminium (7429-90-5) → tetrafluoroaluminate(1-) (21340-02-3) + aluminum(III) fluoride (7784-18-1) + (aluminum trifluoride)2 + AlF2 + AlF4 (1276025-81-0)

Guidance literature:

In solid matrix; react. laser-ablated (10-40 mJ 1064 nm laser energy per 10 ns pulse) Al with F2 in argon or neon matrix at 5 K; identified by IR;

DOI:10.1021/ja1110442

Reference yield:

sodium tetrachloroaluminate (7784-16-9) → tetrafluoroaluminate(1-) (21340-02-3) + AlClF3(1-) (108528-94-5) + AlCl2F2(1-) (109144-15-2) + AlCl3F(1-) (109144-16-3)

Guidance literature:

With NaF; In further solvent(s); byproducts: NaCl; dissolved in molten NaF at 820 ° C (ratio F:Al = 3.0); product ratio detd. by Raman spectroscopy;

upstream raw materials:

aluminium trichloride

aluminium(III) ion

fluoride

adenosine 5'-diphosphate

Refernces

• 1、 Wang, Xuefeng,Andrews, Lester. "Quantum-chemical calculations and IR spectra of the (F2)MF 2 molecules (M = B, Al, Ga, In, Tl) in solid matrices: A new class of very high electron affinity neutral molecules". . p. 3768 - 3771. Retrieved 2011/04/26.
• 2、 Gilbert,Williams, Stephen D.,Mamantov. "Raman spectroscopy of fluoride-containing chloroaluminate melts". . p. 2359 - 2363. Retrieved 2008/10/08.