9-Phenylanthracene

Base Information

• Chemical Name: 9-Phenylanthracene
• CAS No.: 602-55-1
• Molecular Formula: C20H14
• Molecular Weight: 254.331
• Hs Code.: 29029090
• European Community (EC) Number: 210-019-8
• NSC Number: 90796
• UNII: DC63Z5S1UP
• DSSTox Substance ID: DTXSID3075254
• Nikkaji Number: J79.700F
• Wikidata: Q63409533
• Mol file: 602-55-1.mol

Synonyms:9-PHENYLANTHRACENE;602-55-1;Anthracene, 9-phenyl-;9-phenyl-anthracene;DC63Z5S1UP;EINECS 210-019-8;NSC 90796;NSC-90796;NSC90796;MFCD00001252;9-Phenyl-D5-Anthracene;9-Phenylanthracene,98%;9-Phenylanthracene, 98%;UNII-DC63Z5S1UP;DTXSID3075254;AKOS015840536;CS-W012592;DS-6720;FT-0621688;P0138;A869020;A936442;Q63409533;1185864-37-2

Chemical Property of 9-Phenylanthracene

Chemical Property:

• Appearance/Colour: Pale Yellow Plates
• Vapor Pressure: 8.86E-07mmHg at 25°C
• Melting Point: 153-155 °C(lit.)
• Refractive Index: 1.703
• Boiling Point: 417 °C at 760 mmHg
• Flash Point: 192.1 °C
• PSA: 0.00000
• Density: 1.14 g/cm³
• LogP: 5.66000
• Storage Temp.: Sealed in dry,Room Temperature
• Sensitive.: Light Sensitive
• XLogP3: 6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 254.109550447
• Heavy Atom Count: 20
• Complexity: 292

Purity/Quality:

99% ^*data from raw suppliers

9-Phenylanthracene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): N
• Hazard Codes: N
• Statements: 50/53
• Safety Statements: 60-61

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Polycyclic Aromatic Hydrocarbons
• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC=CC3=CC4=CC=CC=C42

Technology Process of 9-Phenylanthracene

There total 123 articles about 9-Phenylanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

9-phenyl-9,10-dihydroanthracene (13577-28-1) → 9-phenylanthracene (602-55-1)

Guidance literature:

With sulfuric acid; oxygen; dioxo(tetramesitylporphyrinato)ruthenium(VI); In benzene; at 50 ℃; for 12h; under 760 Torr;

DOI:10.1055/s-2003-37531

Reference yield: 99.0%

9-Bromoanthracene (1564-64-3) + phenylboronic acid (98-80-6) → 9-phenylanthracene (602-55-1)

Guidance literature:

With potassium phosphate; rac-2,8-bis(diphenylphosphanyl)-4,10-dimethyl-6,12-dihydro-5,11-methanodibenzo[b,f][1,5]diazocine; palladium diacetate; In toluene; at 90 ℃; Schlenk technique; Inert atmosphere;

DOI:10.1002/ejoc.201300519

Reference yield: 98.0%

9-chloroanthracene (716-53-0) + phenylboronic acid (98-80-6) → 9-phenylanthracene (602-55-1)

Guidance literature:

With 4,4'-(phenylphosphinediyl)bis(2,6-dimethylmorpholine); caesium carbonate; tris(dibenzylideneacetone)dipalladium ⁽⁰⁾; In 1,4-dioxane; for 7h; Heating;

DOI:10.1016/j.tet.2006.12.001

upstream raw materials:

chloroform

triphenylmethane

anthracen-9(10H)-one

α,α-Diphenyl-1,2-benzoldimethanol

Downstream raw materials:

9-phenyl-9,10-dihydro-9,10-ethano-anthracene-11,12-dicarboxylic acid-anhydride

9-(4-nitro-phenyl)-10-phenyl-anthracene

9-phenyl-9,10-dihydroanthracene

10-phenyl-10-hydroxy-9-anthracenone

Refernces

• 1、 Sanzone, Alessandro,Calascibetta, Adiel,Ghiglietti, Erika,Ceriani, Chiara,Mattioli, Giuseppe,Mattiello, Sara,Sassi, Mauro,Beverina, Luca. "Suzuki-Miyaura Micellar One-Pot Synthesis of Symmetrical and Unsymmetrical 4,7-Diaryl-5,6-difluoro-2,1,3-benzothiadiazole Luminescent Derivatives in Water and under Air". . p. 15029 - 15042. Retrieved 2018.
• 2、 Lim, Jaewoong,Lee, Seonghwan,Ha, Hyeonbin,Seong, Junmo,Jeong, Seok,Kim, Min,Baek, Seung Bin,Lah, Myoung Soo. "Amine-Tagged Fragmented Ligand Installation for Covalent Modification of MOF-74". . p. 9296 - 9300. Retrieved 2021.
• 3、 Wünsche, Marius A.,Mehlmann, Paul,Witteler, Tim,Buss, Florenz,Rathmann, Patrick,Dielmann, Fabian. "Imidazolin-2-ylidenaminophosphines as Highly Electron-Rich Ligands for Transition-Metal Catalysts". . p. 11857 - 11860. Retrieved 2015.
• 4、 Nandhini, Sundar,Dharani, Sivadasan,Elamathi, Chennakrishnan,Dallemer, Frederic,Prabhakaran, Rathinasabapathi. "Synthesis of tetranuclear complex of Pd(II) with thiosemicarbazone ligands derived from 2-quinolone and its catalytic evaluation in Suzuki–Miyaura-type coupling reactions and alkoxylation of chloroquinolines". . . Retrieved 2021/09/06.
• 5、 -. "Asymmetric antracene derivatives having two phenyl groups and organic light-emitting diode including the same". Paragraph 0305; 0307-0309. . Retrieved 2021/05/11.