10-hydroxy-10-phenyl-9(10H)-anthracenone

Base Information

• Chemical Name: 10-hydroxy-10-phenyl-9(10H)-anthracenone
• CAS No.: 5146-30-5
• Molecular Formula: C20H14O2
• Molecular Weight: 286.33
• Hs Code.: 2914400090
• Mol file: 5146-30-5.mol

Synonyms:10-Hydroxy-10-phenyl-9(10H)-anthracenone;

Chemical Property of 10-hydroxy-10-phenyl-9(10H)-anthracenone

Chemical Property:

• Vapor Pressure: 6.59E-10mmHg at 25°C
• Boiling Point: 477°Cat760mmHg
• Flash Point: 202.7°C
• PSA: 37.30000
• Density: 1.288g/cm³
• LogP: 3.51520

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 10-hydroxy-10-phenyl-9(10H)-anthracenone

There total 70 articles about 10-hydroxy-10-phenyl-9(10H)-anthracenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.9%

9-phenylanthracene (602-55-1) → 10-phenyl-10-hydroxy-9-anthracenone (5146-30-5)

Guidance literature:

With sodium dichromate dihydrate; acetic acid; at 45 ℃; for 1.5h;

DOI:10.1021/acs.orglett.5b02924

Reference yield: 96.0%

9,10-diphenyl-9,10-epidioxyanthracene (15257-17-7) → 10-phenyl-10-hydroxy-9-anthracenone (5146-30-5)

Guidance literature:

With iron(II) chloride; In acetonitrile;

DOI:10.1021/ja035828a

Reference yield: 89.0%

2'-Brom-2-benzoyl-benzophenon (102184-91-8) → 10-phenyl-10-hydroxy-9-anthracenone (5146-30-5)

Guidance literature:

With potassium acetate; tricyclohexylphosphine; hexan-1-ol; palladium diacetate; In N,N-dimethyl-formamide; at 100 ℃; for 24h;

DOI:10.1021/ja000415k

upstream raw materials:

9-methoxy-10-phenylanthracene

10-chloro-10-phenyl-anthrone

9-phenylanthracene

10-phenyl-9-acetoxyanthracene

Downstream raw materials:

10-phenylanthrone

10-(4-hydroxy-phenyl)-10-phenyl-anthrone

9-cyclohexoxy-9-phenylanthrone

9-octoxy-9-phenylanthrone

Refernces

• 1、 Sygula, Andrzej,Sygula, Renata,Fronczek, Frank R.,Rabideau, Peter W.. "Crystal and Molecular Structure of 10-Substituted 9-Anthracenones. Substituent Size as the Controlling Factor for the Nonplanarity of the Central Ring". . p. 3286 - 3291. Retrieved 1992.
• 2、 Stepovik,Malysheva,Fukin. "Interaction of 9-substituted anthracenes with oxidation systems tert-butylhydroperoxide-metal tert-butoxide". . p. 1401 - 1411. Retrieved 2015/08/03.
• 3、 Quan, Long Guo,Lamrani, Mouad,Yamamoto, Yoshinori. "Intramolecular nucleophilic addition of aryl bromides to ketones catalyzed by palladium". . p. 4827 - 4828. Retrieved 2007/10/03.