DIMETHYLCADMIUM

Base Information

• Chemical Name: DIMETHYLCADMIUM
• CAS No.: 506-82-1
• Molecular Formula: C2H6Cd
• Molecular Weight: 142.48
• Hs Code.: 2931900090
• European Community (EC) Number: 208-055-4
• UNII: 0T3G3H597H
• DSSTox Substance ID: DTXSID20964832
• Wikipedia: Dimethylcadmium
• Wikidata: Q27237219
• Mol file: 506-82-1.mol

Synonyms:(CH3)2Cd;DIMETHYLCADMIUM;CADMIUM DIMETHYL;Dimethylcadmiumelecgrcolorlessliq;Dimethylcadmiuminhexane;CADMIUM DIMETHYL 95%;Dimethylcadmium,elec.gr.(99.995+%-Cd)PURATREM;Dimethylcadmium,min.97%

Chemical Property of DIMETHYLCADMIUM

Chemical Property:

• Appearance/Colour: colorless toxic liquid
• Melting Point: -4.5 °C
• Refractive Index: nD 1.5488
• Boiling Point: 105.5 °C
• Flash Point: -18 °C
• PSA: 0.00000
• Density: 1.986 g/cm³
• LogP: 1.16510
• Sensitive.: moisture sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 143.950315
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98% ^*data from raw suppliers

Dimethylcadmium, elec. gr. (99.995+%-Cd) PURATREM ^*data from reagent suppliers

Safty Information:

• Statements: 17-20/21/22
• Safety Statements: 7/8-16-23-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Metals -> Metals, Organic Compounds
• Canonical SMILES: [CH3-].[CH3-].[Cd+2]
• Uses: In organic synthesis; as polymerization catalyst.

Technology Process of DIMETHYLCADMIUM

There total 13 articles about DIMETHYLCADMIUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

→ dimethylcadmium (506-82-1)

Guidance literature:

Reference yield: 23.0%

tin(IV) iodide + bis(trifluoromethyl)cadmium*glyme → trimethyl(trifluoromethyl)tin (754-25-6) + dimethylcadmium (506-82-1) + dimethylbis(trifluoromethyl)tin (65059-36-1)

Guidance literature:

In dichloromethane; byproducts: Sn(CH3)4, C2F4, CH3I; excess of Cd compd. quickly added to SnI4 in CH2Cl2, sepd. after 15 min; solvent removed;

DOI:10.1021/ja00401a015

Reference yield:

methyl magnesium iodide (917-64-6) → dimethylcadmium (506-82-1)

Guidance literature:

With cadmium(II) chloride;

DOI:10.1021/ja01525a044 DOI:10.1021/j150494a001

upstream raw materials:

methyl magnesium iodide

methylmagnesium bromide

diethyl ether

methyl iodide

Downstream raw materials:

3,3-Dimethyl-3H-isobenzofuran-1-one

2-acetyl-benzoic acid

1-(1-phenylcyclohexyl)ethanone

2-heptanone, 5-methyl-

Refernces

• 1、 Emptoz,Huet. "-". . p. 139,140, 149. Retrieved 1974.
• 2、 Juhlke et al.. "". . p. 3229. Retrieved 1979.
• 3、 Saxena, Priya,Thirupathi, Natesan. "Reactions of Cd(OAc)2·2H2O with variously substituted pyridines. Efforts to unravel the factors that determine structure/nuclearity of the products". . p. 238 - 250. Retrieved 2015.
• 4、 -. "Method for treating cancers using a diiodo thyronine analogue having no significant hormonal activity and a vinca alkaloid and compositions comprising the same". . . Retrieved 2008/06/13.