Stannane, dimethylbis(trifluoromethyl)-

Base Information

• Chemical Name: Stannane, dimethylbis(trifluoromethyl)-
• CAS No.: 65059-36-1
• Molecular Formula: C4H6F6Sn
• Molecular Weight: 286.792
• Mol file: 65059-36-1.mol

Synonyms:

Chemical Property of Stannane, dimethylbis(trifluoromethyl)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Stannane, dimethylbis(trifluoromethyl)-

There total 2 articles about Stannane, dimethylbis(trifluoromethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

tin(IV) iodide + bis(trifluoromethyl)cadmium*glyme → trimethyl(trifluoromethyl)tin (754-25-6) + dimethylcadmium (506-82-1) + dimethylbis(trifluoromethyl)tin (65059-36-1)

Guidance literature:

In dichloromethane; byproducts: Sn(CH3)4, C2F4, CH3I; excess of Cd compd. quickly added to SnI4 in CH2Cl2, sepd. after 15 min; solvent removed;

DOI:10.1021/ja00401a015

Reference yield:

bis(trifluoromethyl)mercury (371-76-6) + hexamethyldistannane (661-69-8) → tetramethylstannane (594-27-4) + trimethyl(trifluoromethyl)tin (754-25-6) + dimethylbis(trifluoromethyl)tin (65059-36-1)

Guidance literature:

In not given; byproducts: Hg, C3F6; absence of air and moisture; heating of Hg-compd. with slight excess of Sn-compd. (sealed tube, 75°C, 1 week); product mixt. not sepd., detd. by (1)H-NMR spectroscopy;

DOI:10.1039/DT9780000541

upstream raw materials:

bis(trifluoromethyl)mercury

hexamethyldistannane

Refernces