Bromopentacarbonylrhenium

Base Information

• Chemical Name: Bromopentacarbonylrhenium
• CAS No.: 14220-21-4
• Molecular Formula: C5Br O5 Re
• Molecular Weight: 406.163
• Hs Code.: 29310099
• European Community (EC) Number: 238-084-8
• Wikipedia: Bromopentacarbonylrhenium(I)
• Mol file: 14220-21-4.mol

Synonyms:14220-21-4;Bromopentacarbonylrhenium;bromorhenium;carbon monoxide;(i);C5BrO5Re;ReBr(CO)5;bromopentacar-bonylrhenium;C5-Br-O5-Re;Rhenium, bromopentacarbonyl-;Bromopentacarbonylrhenium(I), 98%;CS-0106109;Rhenium, bromopentacarbonyl-, (OC-6-22)-;E77059;Rhenium,bromopentacarbonyl-, (OC-6-22)- (9CI);J-007618

Chemical Property of Bromopentacarbonylrhenium

Chemical Property:

• Appearance/Colour: Off-white crystalline powder
• Melting Point: 90°C (subl.)
• PSA: 0.00000
• LogP: -0.19440
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Moisture Sensitive
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 0
• Exact Mass: 405.84866
• Heavy Atom Count: 12
• Complexity: 12

Purity/Quality:

98%,99%, ^*data from raw suppliers

Bromopentacarbonylrhenium(I) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 23/24/25-36/37/38
• Safety Statements: 26-28-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].Br[Re]
• Uses: This is used to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands and also to prepare [3]-ferrocenophane complexes. The starting material for rhenium-polypyridine complexes that have potential applications in catalysis and solar energy conversion.

Technology Process of Bromopentacarbonylrhenium

There total 51 articles about Bromopentacarbonylrhenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

decacarbonyldirhenium(0) (14285-68-8) + bromine (7726-95-6) → rhenium(I) pentacarbonyl bromide (14220-21-4)

Guidance literature:

In carbon disulfide; for 2h;

DOI:10.1021/acs.inorgchem.9b01656

Reference yield: 94.0%

decacarbonyldirhenium(0) (14285-68-8) + sodium bromide (7647-15-6) → rhenium(I) pentacarbonyl bromide (14220-21-4)

Guidance literature:

With Oxone; In neat (no solvent); for 0.0833333h; Time; Milling;

DOI:10.1039/c4sc01252f

Reference yield: 90.0%

decacarbonyldirhenium(0) (14285-68-8) → rhenium(I) pentacarbonyl bromide (14220-21-4)

Guidance literature:

With Br₂; In carbon disulfide; Br2 was added dropwise to stirring soln. of complex at 25°C (N2)for 10 min; evapn., sublimation;

upstream raw materials:

formic acid

hydrogen bromide

decacarbonyldirhenium⁽⁰⁾

bromine

Downstream raw materials:

9-fluorenone

9,10-phenanthrenequinone

(CO)3ReBrC₁₀N₂H₆[CONHC₂H₄NHCOC₆H₃(OCH₃)2]2

[ReBr(CO)3(C₅₄H₅₆N₂O₁₀)]

Refernces

• 1、 Chen, Chang-Hung,Liu, Yi-Hung,Peng, Shie-Ming,Chen, Jwu-Ting,Liu, Shiuh-Tzung. "Synthesis of N-heterocyclic carbene rhenium(i) carbonyl complexes". . p. 2747 - 2754. Retrieved 2012.
• 2、 Sokolov,Villagra,El-Hendawy,Kwak,Elsegood,Clegg,Geoffrey Sykes. "Preparation and properties of heterometallic cube derivatives Mo3M′S4 from [Mo3S4(H2O)9]4+ with M′ = 3 Pt, Rh and Re, and [W3S4(H2O)9]". . p. 2611 - 2615. Retrieved 2001.
• 3、 Strickland, Debra S.,Wilson, Scott R.,Shapley, John R.. "Generation and reactivity of a triosmium carbon radical. Hydrogen abstraction, arene addition, and the formation of [H3Os3(CO)9(μ3-CCO)]2, a dialkylidyne, diketone complex". . p. 1674 - 1676. Retrieved 1988.
• 4、 Machado, Ignacio,Fernandez, Soledad,Becco, Lorena,Garat, Beatriz,Gancheff, Jorge S.,Rey, Ana,Gambino, Dinorah. "New fac -tricarbonyl rhenium(I) semicarbazone complexes: Synthesis, characterization, and biological evaluation". . p. 1835 - 1850. Retrieved 2014.
• 5、 Ndinguri, Margaret W.,Black, Carrie A.,Gosser, Anna L.,Reitz, Sara,Sutphin, Cody,Fronczek, Frank R.,Cormier, Lindsay E.. "Exploring the synthesis and characterization of fac-Re(CO)3L complexes using diethylenetriamine derivative functionalized at the central nitrogen". . . Retrieved 2021.