Methyl (E)-4-chloro-3-methoxy-2-butenoate

Base Information Edit

Chemical Name:Methyl (E)-4-chloro-3-methoxy-2-butenoate
CAS No.:110104-60-4
Molecular Formula:C6H9ClO3
Molecular Weight:164.589
Hs Code.:29189990
European Community (EC) Number:285-842-9,679-649-2
Nikkaji Number:J461.227B
Mol file:110104-60-4.mol

Synonyms:110104-60-4;(E)-Methyl 4-chloro-3-methoxybut-2-enoate;Methyl (E)-4-chloro-3-methoxy-2-butenoate;Methyl 4-chloro-3-methoxy-2-(E)-butenoate;(E)-4-Chloro-3-methoxy-2-butenoic Acid Methyl Ester;methyl (E)-4-chloro-3-methoxybut-2-enoate;Methyl E-4-chloro-3-methoxy-2-butenoate;85153-60-2;MFCD00071562;4-chloro-3-methoxy-2-E-butenoic acid methyl ester;4-Chloro-3-methoxy-2(E)-butenoic acid methyl ester;SCHEMBL1066497;JNYMRXDQVPIONI-HWKANZROSA-N;AKOS006221479;CS-W001859;DS-4809;(E)-Methyl4-chloro-3-methoxybut-2-enoate;Methyl(E)-4-chloro-3-methoxy-2-butanoate;Methyl (E)-4-chloro-3-methoxy-2-butanoate;methyl (2E)-4-chloro-3-methoxybut-2-enoate;EN300-379478;S11671;3-methoxy-4-chloro-2E-butenoic acid methyl ester;4-chloro-3-methoxy-2E-butenoic acid methyl ester;4-chloro-3-methoxybut-2E-enoic acid methyl ester;A802140;4-chloro-3-methoxy-2-E-butenoic acid, methyl ester;4-chloro-3-methoxy-but-2E-enoic acid methyl ester;J-640345;METHYL (2E)-4-CHLORO-3-METHOXY-2-BUTENOATE;(E)-4-chloro-3-methoxy-but-2-enoic acid methyl ester

Suppliers and Price of Methyl (E)-4-chloro-3-methoxy-2-butenoate

Supply Marketing:Edit

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl (E)-4-Chloro-3-methoxy-2-butenoate
500mg
$ 75.00

TCI Chemical
Methyl (E)-4-Chloro-3-methoxy-2-butenoate >95.0%(GC)
25g
$ 242.00

TCI Chemical
Methyl (E)-4-Chloro-3-methoxy-2-butenoate >95.0%(GC)
5g
$ 82.00

SynQuest Laboratories
Methyl (2E)-4-chloro-3-methoxybut-2-enoate 95%
25 g
$ 144.00

Crysdot
(E)-Methyl4-chloro-3-methoxybut-2-enoate 95+%
25g
$ 141.00

Apolloscientific
Methyl (2E)-4-chloro-3-methoxybut-2-enoate
25g
$ 122.00

Ambeed
(E)-Methyl4-chloro-3-methoxybut-2-enoate 95%
100g
$ 337.00

Ambeed
(E)-Methyl4-chloro-3-methoxybut-2-enoate 95%
10g
$ 63.00

Ambeed
(E)-Methyl4-chloro-3-methoxybut-2-enoate 95%
5g
$ 34.00

Ambeed
(E)-Methyl4-chloro-3-methoxybut-2-enoate 95%
1g
$ 10.00

Total 41 raw suppliers

Chemical Property of Methyl (E)-4-chloro-3-methoxy-2-butenoate Edit

Chemical Property:

Appearance/Colour:clear yellow liquid after melting
Vapor Pressure:0.0643mmHg at 25°C
Melting Point:25 °C
Refractive Index:1.483-1.485
Boiling Point:230.864 °C at 760 mmHg
Flash Point:98.995 °C
PSA：35.53000
Density:1.157 g/cm³
LogP:0.92850
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
Water Solubility.:Insoluble
XLogP3:0.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:4
Exact Mass:164.0240218
Heavy Atom Count:10
Complexity:142

Purity/Quality:

99% ^*data from raw suppliers

Methyl (E)-4-Chloro-3-methoxy-2-butenoate ^*data from reagent suppliers

Safty Information:

Pictogram(s): C
Hazard Codes:C
Statements: 34-22
Safety Statements: 45-36/37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:COC(=CC(=O)OC)CCl
Isomeric SMILES:CO/C(=C/C(=O)OC)/CCl

Technology Process of Methyl (E)-4-chloro-3-methoxy-2-butenoate

There total 3 articles about Methyl (E)-4-chloro-3-methoxy-2-butenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.4%

: 67-56-1
methanol

: 32807-28-6,935731-94-5
Methyl 4-chloroacetoacetate

: 110104-60-4,85153-60-2
(E)-4-chloro-3-methoxy-but-2-enoic acid methyl ester

Guidance literature:: methanol; Methyl 4-chloroacetoacetate; With thionyl chloride; at -10 - 20 ℃;

With methanesulfonic acid; at 150 ℃; under 75.006 Torr;
DOI:10.1016/S0040-4020(02)00178-3

Reference yield:

: 41295-64-1
4-chloroacetoacetyl chloride

: 110104-60-4,85153-60-2
(E)-4-chloro-3-methoxy-but-2-enoic acid methyl ester

Guidance literature:: With hydrogenchloride; sodium hydroxide; methanesulfonic acid; sodium chloride; In thionyl chloride; dichloromethane; toluene;