Acetic acid, 2,2,2-trifluoro-, 2-Methylpropyl ester

Base Information

• Chemical Name: Acetic acid, 2,2,2-trifluoro-, 2-Methylpropyl ester
• CAS No.: 17355-83-8
• Molecular Formula: C6H9F3O2
• Molecular Weight: 170.131
• Mol file: 17355-83-8.mol

Synonyms:Trifluoroacetic acid,2-methylpropyl ester;Isobutyl trifluoroacetate;Acetic acid,trifluoro-,2-methylpropyl ester;Isobutyltrifluoracetat;Trifluoressigsaeure-isobutylester;isobutyl triflate;

Chemical Property of Acetic acid, 2,2,2-trifluoro-, 2-Methylpropyl ester

Chemical Property:

• PSA: 26.30000
• LogP: 1.74790

Purity/Quality:

99.90% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Acetic acid, 2,2,2-trifluoro-, 2-Methylpropyl ester

There total 3 articles about Acetic acid, 2,2,2-trifluoro-, 2-Methylpropyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Isobutane (75-28-5,40921-86-6) + carbon monoxide (201230-82-2) + trifluoroacetic acid (76-05-1) → formic acid (64-18-6) + trifluoroacetic acid-methyl ester (431-47-0) + isopropyl Trifluoroacetate (400-38-4) + isobutyl trifluoroacetate (17355-83-8) + butanone (78-93-3)

Guidance literature:

With rhodium(III) chloride; oxygen; copper(II) trifluoroacetate; sodium chloride; In water; at 80 ℃; under 45004.5 Torr; Autoclave; Inert atmosphere;

DOI:10.1134/S0023158410050071

Reference yield:

Isobutane (75-28-5,40921-86-6) + trifluoroacetic acid (76-05-1) → formic acid (64-18-6) + trifluoroacetic acid-methyl ester (431-47-0) + isopropyl Trifluoroacetate (400-38-4) + isobutyl trifluoroacetate (17355-83-8)

Guidance literature:

With carbon monoxide; rhodium(III) trichloride hydrate; water; oxygen; copper(II) oxide; at 80 ℃; for 2h; Inert atmosphere; Autoclave;

DOI:10.1134/S0965544110050026

Reference yield:

Isobutane (75-28-5,40921-86-6) + trifluoroacetic acid-d1 (599-00-8) + carbon monoxide (201230-82-2) → Isopropanol-d1 (3979-51-9) + iso-BuOD (14848-63-6) + formic acid-d1 (925-94-0) + trifluoroacetic acid-methyl ester (431-47-0) + isopropyl Trifluoroacetate (400-38-4) + isobutyl trifluoroacetate (17355-83-8)

Guidance literature:

With rhodium(III) chloride; water-d2; oxygen; copper(II) trifluoroacetate; sodium chloride; at 95 ℃; for 2.5h; under 48004.8 Torr; Kinetics; Mechanism; Autoclave; Inert atmosphere;

DOI:10.1134/S0023158410050071

upstream raw materials:

Isobutane

trifluoroacetic acid-d₁

carbon monoxide

trifluoroacetic acid

Downstream raw materials:

1,3,5-Triisopropyl-2-[(R)-1-(4-methyl-pent-1-ynyloxy)-ethyl]-benzene

Refernces

• 1、 Chepaikin,Bezruchenko,Menchikova,Moiseeva,Gekhman. "Catalytic oxidation of hydrocarbons of natural and oil gas". experimental part. p. 332 - 337. Retrieved 2011/04/26.