Bis(2-ethylhexyl) ether

Base Information

• Chemical Name: Bis(2-ethylhexyl) ether
• CAS No.: 10143-60-9
• Molecular Formula: C16H34 O
• Molecular Weight: 242.445
• Hs Code.: 2909199090
• European Community (EC) Number: 233-412-6
• UNII: 293357T1G3
• DSSTox Substance ID: DTXSID5042035
• Nikkaji Number: J34.762K
• Wikidata: Q27254371
• Mol file: 10143-60-9.mol

Synonyms:10143-60-9;BIS(2-ETHYLHEXYL) ETHER;3-(2-ethylhexoxymethyl)heptane;2-Ethylhexyl Ether;di(2-ethylhexyl)ether;Heptane, 3,3'-[oxybis(methylene)]bis-;Ether, bis(2-ethylhexyl);Di-(2-ethylhexyl) ether;BRN 1748359;Heptane, 3,3'-(oxybis(methylene))bis-;Di-2-ethylhexyl ether;Hexane, 1,1'-oxybis(2-ethyl-;Di(2-ethylhexyl) ether;EINECS 233-412-6;UNII-293357T1G3;293357T1G3;Ethylhexyl oxide;Heptane,3,3'-[oxybis(methylene)]bis-;SCHEMBL80432;DTXSID5042035;3-((2-ethylhexyloxy)methyl)heptane;MFCD00059427;AKOS028108407;LS-67734;D1021;FT-0745962;D89764;Q27254371

Chemical Property of Bis(2-ethylhexyl) ether

Chemical Property:

• Vapor Pressure: 0.00762mmHg at 25°C
• Melting Point: 269
• Refractive Index: 1.4320-1.4380
• Boiling Point: 277.5 °C at 760 mmHg
• Flash Point: 107.5 °C
• PSA: 9.23000
• Density: 0.808 g/cm³
• LogP: 5.43580
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• XLogP3: 6.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 12
• Exact Mass: 242.260965704
• Heavy Atom Count: 17
• Complexity: 129

Purity/Quality:

98%,99%, ^*data from raw suppliers

EthylhexylOxide(>85%) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCC(CC)COCC(CC)CCCC
• Uses: Derivative of Ethylhexyl Oxide over Nafion-H are highly efficient solid perfluoroalkanesulfonic acid catalyst.

Technology Process of Bis(2-ethylhexyl) ether

There total 13 articles about Bis(2-ethylhexyl) ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

d,l-2-ethylhexanal (123-05-7) + benzaldehyde (100-52-7) → bis(2-ethylhexyl)ether (10143-60-9) + dibenzyl ether (103-50-4) + Benzyl-<2-aethyl-hexyl>-aether (92860-02-1)

Guidance literature:

With triethylsilane; silver(I) bis(trifluoromethanesulfonyl)imide; In dichloromethane; at 25 ℃; for 0.5h;

DOI:10.1021/acs.orglett.2c00270

Reference yield: 80.0%

d,l-2-ethylhexanal (123-05-7) + phenylacetaldehyde (122-78-1) → bis(2-ethylhexyl)ether (10143-60-9) + di(2-phenylethyl) ether (2396-53-4) + (2-((2-ethylhexyl)oxy)ethyl)benzene

Guidance literature:

With triethylsilane; silver(I) bis(trifluoromethanesulfonyl)imide; In dichloromethane; at 25 ℃; for 0.5h;

DOI:10.1021/acs.orglett.2c00270

Reference yield:

2-ethylhexenal (645-62-5) → bis(2-ethylhexyl)ether (10143-60-9)

Guidance literature:

With 5% palladium on Al₂O₃; hydrogen; at 150 ℃; for 12h; under 30003 Torr; Autoclave;

upstream raw materials:

2-Ethylhexyl alcohol

2-ethylhexenal

d,l-2-ethylhexanal

benzaldehyde

Refernces

• 1、 -. "METHOD FOR PRODUCING ETHER COMPOUND". Paragraph 0059-0062; 0064; 0066; 0068; 0070; 0072; 0074. . Retrieved 2021/03/13.
• 2、 -. "HIGHLY EFFICIENT METHOD FOR PRODUCING SATURATED HOMOETHER FROM UNSATURATED CARBONYL COMPOUND". Paragraph 0041; 0045-0046; 0048. . Retrieved 2020/07/16.