2396-53-4

Basic information

• Product Name: di(2-phenylethyl) ether
• Synonyms: di(2-phenylethyl) ether
• CAS NO: 2396-53-4
• Molecular Weight: 226.318
• Mol File: 2396-53-4.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: di(2-phenylethyl) ether(CAS DataBase Reference)
• NIST Chemistry Reference: di(2-phenylethyl) ether(2396-53-4)
• EPA Substance Registry System: di(2-phenylethyl) ether(2396-53-4)

Safety Data

• Hazardous Substances Data: 2396-53-4(Hazardous Substances Data)

Upstream product

• 60-12-8 2-phenylethanol 
• 112-54-9 Dodecanal 
• 122-78-1 phenylacetaldehyde 
• 123-72-8 butyraldehyde 
• 123-05-7 d,l-2-ethylhexanal 
• 617-86-7 triethylsilane 
• 98-85-1 1-Phenylethanol 
• 102-20-5 phenyl-acetic acid phenethyl ester 
• 4794-16-5 ethylbenzene hydroperoxide 
• 3282-32-4 2-diazo-acetophenone 
• 109-78-4 3-Hydroxypropionitrile 
• 108-93-0 cyclohexanol 
• 542-59-6 2-hydroxyethyl acetate 
• 24281-43-4 sulfurous acid diphenethyl ester 

Downstream Products

• 67662-96-8 2-phenethyl pivalate 
• 622-24-2 2-phenylethyl chloride 
• 1647-26-3 1-bromo-2-cyclohexylethane 
• 103-45-7 acetic acid phenethyl ester 
• 55255-91-9 bis-(2-cyclohexyl-ethyl)-ether 
• 94-47-3 2-Phenylethyl benzoate 

Relevant articles and documents

Synthesis of ethers from esters via Fe-catalyzed hydrosilylation

Triiron dodecacarbonyl allows for the selective reduction of esters into the corresponding ethers. This protocol has a wide substrate scope. In addition, cholesteryl pelarogonate has been reduced under the reaction conditions with an excellent yield.

Breaking C-O Bonds with Uranium: Uranyl Complexes as Selective Catalysts in the Hydrosilylation of Aldehydes

We report herein the possibility to perform the hydrosilylation of carbonyls using actinide complexes as catalysts. While complexes of the uranyl ion [UO2]2+ have been poorly considered in catalysis, we show the potentialities of the Lewis acid [UO2(OTf)2] (1) in the catalytic hydrosilylation of a series of aldehydes. [UO2(OTf)2] proved to be a very active catalyst affording distinct reduction products depending on the nature of the reductant. With Et3SiH, a number of aliphatic and aromatic aldehydes are reduced into symmetric ethers, while iPr3SiH yielded silylated alcohols. Studies of the reaction mechanism led to the isolation of aldehyde/uranyl complexes, [UO2(OTf)2(4-Me2N-PhCHO)3], [UO2(μ-κ2-OTf)2(PhCHO)]n, and [UO2(μ-κ2-OTf)(κ1-OTf)(PhCHO)2]2, which have been fully characterized by NMR, IR, and single-crystal X-ray diffraction.

An ether compound of green high-efficient synthetic method (by machine translation)

The invention discloses an ether compound of green high-efficient synthetic method, energy-saving environmental protection, comprising: mild reaction system, uses aldehyde, silane as the starting material, under the action of the silver salt in a price, for in solvent-free conditions, through reducing the - coupling - cheng mi reaction, realization of high efficiency alcohol of preparation. Synthesis method of the invention has the advantages of low dosage of catalyst, solvent-free, conversion and high yield, the reaction time is short, safe and stable, easy to operate, the product only distillation purification without any additional organic solvent, the whole range of green, environmental protection, high efficiency and the like, can overcome the defects of the prior art, it has very good industrial application value. (by machine translation)