Lhcgbifhsccrrg-uhfffaoysa-

Base Information

• Chemical Name: Lhcgbifhsccrrg-uhfffaoysa-
• CAS No.: 10325-39-0
• Molecular Formula: BCl2 H
• Molecular Weight: 82.7249
• Nikkaji Number: J236.766A
• Mol file: 10325-39-0.mol

Synonyms:LHCGBIFHSCCRRG-UHFFFAOYSA-

Chemical Property of Lhcgbifhsccrrg-uhfffaoysa-

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 0.99820
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 81.9548356
• Heavy Atom Count: 3
• Complexity: 2.8

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: B(Cl)Cl

Technology Process of Lhcgbifhsccrrg-uhfffaoysa-

There total 53 articles about Lhcgbifhsccrrg-uhfffaoysa- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

monochlorodiborane (17927-57-0) + boron trichloride (10294-34-5) → dichloroborane (10325-39-0)

Guidance literature:

in presence of fluid BCl3; 100 % conversion at 20°C in 1 week; more than 60 % B2H5Cl reacts at 30°C in 4 h;

DOI:10.1021/ic50007a067

Reference yield: 86.4%

hydrogen (1333-74-0) + boron trichloride (10294-34-5) → dichloroborane (10325-39-0)

Guidance literature:

With magnesium; In gas; flowing H2/BCl3 gas mixt. over Mg heated to 440°C; molar ratio H2:BCl3 = 7.9:1;

Reference yield: 73.0%

pentaborane(9) + diboron tetrachloride (13701-67-2) → monochlorodiborane (17927-57-0) + 1-(dichloroboryl)pentaborane + dichloroborane (10325-39-0) + boron trichloride (10294-34-5) + diborane (19287-45-7)

Guidance literature:

In neat (no solvent); reaction carried out in Pyrex tubes to which Teflon valves had been sealed or in a N2-filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1:3 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 20 min at ambient temp.,; fractionation, yield of 1-BCl2B5H8 based upon amt. of B2Cl4 employed: 73%, based upon amt. of B5H9 consumed: 95%; small amts. of B2H6, BCl2H, B2H5Cl, also material insufficiently volatileto move into vac. line formed;;

upstream raw materials:

boron trichloride

diborane

hydrogen

monochlorodiborane

Downstream raw materials:

2-dichloroboryl-2-methyl-2-(3-dichloroboryl-4-methylcyclohexyl)ethane

monochlorodiborane

diborane

boron trichloride

Refernces

• 1、 Lee, Kuk-Haeng,Takeo, Harutoshi,Kondo, Shigeo,Matsumura, Chi. "Infrared Spectrum of Dichloroborane Produced by CO2 Laser Enhanced Reaction". . p. 1772 - 1777. Retrieved 1985.
• 2、 Hurd, D. T.. "". . p. 20 - 22. Retrieved 1949.
• 3、 Brown, H. C.,Tierney, P. A.. "". . p. 51 - 55. Retrieved 1959.
• 4、 Nadeau, H. G.,Oaks, D. M.. "". . p. 1480 - 1484. Retrieved 1960.
• 5、 Urry et al.. "". . . Retrieved 1954.
• 6、 Saulys,Morrison. "Reactions of the diboron tetrahalides B2Cl4 and B2Br4 with B5H9: Preparation and properties of the (dihaloboryl)pentaborane derivatives 1-BX2B5H8, (X = Br, Cl, F, OCH3, t-Bu, H) and synthesis of (BCl2)3B5H6". . p. 4174 - 4179. Retrieved 2008/10/08.