17927-57-0Relevant articles and documents
Hydroboration with haloborane/trialkylsilane mixtures
Soundararajan, Raman,Matteson, Donald S.
, p. 4157 - 4166 (2008/10/09)
Trialkylsilanes or dialkylsilanes react rapidly with boron trichloride in the absence of ethereal solvents or other nucleophiles to form unsolvated dichloroborane. If no substrate is present, dichloroborane disproportionates to trichloroborane and two geo
Reactions of pentaborane(9) and pentaborane derivatives
Onak, Thomas,Dunks, Gary B.,Searcy, I. William,Spielman
, p. 1465 - 1471 (2007/12/19)
The preparations of a number of pentaborane derivatives are described and 11B and 1H nmr spectra recorded and correlated. Assessments of alternative preparative schemes are given. An extension of the apex to base rearrangement reaction to polyalkyl pentaboranes reveals the following trends: the rate of rearrangement decreases with increasing number of alkyl substituents on the pentaborane framework; the rate increases with the use of stronger and less sterically hindered bases. Mechanistic inferences are discussed.
On the properties of monochlorodiborane
Myers, Hulon W.,Putnam, Roy F.
, p. 655 - 657 (2008/10/08)
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