bicyclo[2.2.0]hexane

Base Information

• Chemical Name: bicyclo[2.2.0]hexane
• CAS No.: 186-04-9
• Molecular Formula: C6H10
• Molecular Weight: 82.1454
• Mol file: 186-04-9.mol

Synonyms:

Chemical Property of bicyclo[2.2.0]hexane

Chemical Property:

• Vapor Pressure: 87.6mmHg at 25°C
• Boiling Point: 82.4°Cat760mmHg
• Flash Point: °C
• Density: 0.939g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bicyclo[2.2.0]hexane

There total 5 articles about bicyclo[2.2.0]hexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 0.4%

2,3-diazabicyclo<2.2.2>oct-2-ene (3310-62-1) → 1,5-Hexadien (592-42-7) + cyclohex-3-enone (4096-34-8) + bicyclo[2.2.0]hexane (186-04-9) + 2,3-dioxabicyclo[2.2.2]octane (280-53-5) + cyclohex-3-enyl hydroperoxide (4096-33-7)

Guidance literature:

With benzophenone; oxygen; In trichlorofluoromethane; at -20 ℃; for 8h; under 7600 Torr; Mechanism; Irradiation; oxygen trapping of the intermediate triplet biradical 1,4-cyclohexadiyl;

DOI:10.1021/ja00336a069

Reference yield:

1,5-Hexadien (592-42-7) → cis-bicyclo<2.2.0>hexane (186-04-9,72033-85-3) + bicyclo[2.1.0]pentane (185-94-4) + 2'-propenylcyclopropane (4663-23-4)

Guidance literature:

With mercury; for 96h; Heating; Irradiation;

DOI:10.1039/P29880001371

Reference yield:

2,3-diazabicyclo[2.2.2]oct-2-ene (3310-62-1) → 1,5-Hexadien (592-42-7) + bicyclo[2.2.0]hexane (186-04-9)

Guidance literature:

In pentane; for 0.0833333h; Product distribution; Quantum yield; Irradiation; λ = 185 nm; other times, λ;

DOI:10.1021/ja00543a055

upstream raw materials:

1,5-Hexadien

2,3-diazabicyclo[2.2.2]oct-2-ene

2,3-diazabicyclo<2.2.2>oct-2-ene

Downstream raw materials:

bromobenzene

4-bromocyclohexene

trans-1,4-dibromocyclohexane

cis-1,4-dibromocyclohexane

Refernces

• 1、 Anderson, Mark A.,Grissom, Charles B.. "Increasing the heavy atom effect of xenon by adsorption to zeolites: Photolysis of 2,3-diazabicyclo[2.2.2]oct-2-ene". . p. 9552 - 9556. Retrieved 1996.
• 2、 Adam, Waldemar,Hannemann, Klaus,Wilson, R. Marshall. "UV-Laser Photochemistry of the Azoalkane 2,3-Diazabicyclooct-2-ene: Trapping of the Short-Lived, Triplet Biradical 1,4-Cyclohexadiyl by Molecular Oxygen". . p. 7646 - 7647. Retrieved 1984.
• 3、 Walton, John C.. "Homolytic Rearrangements of Bicyclohexane and Bicycloheptane". . p. 1371 - 1376. Retrieved 2007/10/02.