2-Bromoindene

Base Information

• Chemical Name: 2-Bromoindene
• CAS No.: 10485-09-3
• Molecular Formula: C9H7Br
• Molecular Weight: 195.059
• Hs Code.: 29036990
• Mol file: 10485-09-3.mol

Synonyms:Indene,2-bromo- (6CI,8CI);2-Bromo-1H-indene;2-Indenyl bromide;

Chemical Property of 2-Bromoindene

Chemical Property:

• Appearance/Colour: Yellow to pale brown low melting solid
• Vapor Pressure: 0.0241mmHg at 25°C
• Melting Point: 35-37 °C
• Refractive Index: 1.659
• Boiling Point: 256.9 °C at 760 mmHg
• Flash Point: 113 °C
• PSA: 0.00000
• Density: 1.57 g/cm³
• LogP: 2.97850
• Storage Temp.: Refrigerator (+4°C)
• Water Solubility.: Insoluble in water.

Purity/Quality:

99% ^*data from raw suppliers

2-Bromoindene ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 37/39-26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 2-Bromoindene is used as pharmaceutical intermediate.

Technology Process of 2-Bromoindene

There total 18 articles about 2-Bromoindene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(1H-inden-2-yl)triisopropylsilane (1352210-71-9) → 2-bromoindene (10485-09-3)

Guidance literature:

With N-Bromosuccinimide; 1,1,1,3',3',3'-hexafluoro-propanol; In dichloromethane; for 0.166667h;

DOI:10.1021/ol203209b

Reference yield: 90.0%

trans-2-bromo-1-indanol (10368-44-2,78684-69-2) → 2-bromoindene (10485-09-3)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; for 4h; Heating;

DOI:10.1021/ja00063a019

Reference yield: 86.2%

→ 2-bromoindene (10485-09-3)

Guidance literature:

upstream raw materials:

trans-1,2-bromoindane

trans-2-bromo-1-indanol

2-bromo-1-indanol

1,2-dibromoindane

Downstream raw materials:

2-(phenylsilyl)indene

(1H-inden-2-yl)dimethyl(phenyl)silane

2,2'-diphenylbiphenyl

2-(2-phenylethynyl)-1H-indene

Refernces

• 1、 Rimkus, Andrea M.,Alt, Helmut G.. "Dissymmetric ansa zirconocene complexes with di- and trisubstituted indenyl ligands as catalysts for homogeneous ethylene homo- and ethylene/1-hexene copolymerization reactions". . p. 72 - 82. Retrieved 2017.
• 2、 Hofstra, Julie L.,Poremba, Kelsey E.,Shimozono, Alex M.,Reisman, Sarah E.. "Nickel-Catalyzed Conversion of Enol Triflates into Alkenyl Halides". supporting information. p. 14901 - 14905. Retrieved 2019/11/11.