Azulene, 1-chloro-

Base Information

• Chemical Name: Azulene, 1-chloro-
• CAS No.: 23306-02-7
• Molecular Formula: C10H7Cl
• Molecular Weight: 162.619
• Mol file: 23306-02-7.mol

Synonyms:

Chemical Property of Azulene, 1-chloro-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Azulene, 1-chloro-

There total 1 articles about Azulene, 1-chloro- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

azulene (275-51-4) → 1,3-dichloroazulene (14658-94-7) + 1-chloroazulene (23306-02-7)

Guidance literature:

With dichloromethane; Quantum yield; Irradiation; other chlorination agent;

DOI:10.1021/jo00081a024

Reference yield: 92.0%

1-chloroazulene (23306-02-7) → azulene (275-51-4)

Guidance literature:

With potassium phosphate; poly(methylhydrosiloxane); palladium diacetate; In tetrahydrofuran; at 80 ℃; for 12h;

DOI:10.1002/anie.200501276

Reference yield: 81.0%

1-chloroazulene (23306-02-7) + 1,2-bis(4-methoxyphenyl)-1,2-ethanediol (4464-76-0,39090-28-3,39090-30-7,42565-21-9,66768-20-5,122798-27-0) → 2-[3-(1-chloroazulenyl)]-1,1-bis(4-methoxyphenyl)ethylene

Guidance literature:

With hydrogenchloride; In methanol; at 60 ℃; for 3h;

DOI:10.1016/j.tet.2004.05.022

upstream raw materials:

azulene

Downstream raw materials:

1-phenylazo-3-chloroazulene

3-Chlor-1-triphenylmethyl-azulen

azulene

Refernces

• 1、 Cowper, Paul,Pockett, Adam,Kociok-K?hn, Gabriele,Cameron, Petra J.,Lewis, Simon E.. "Azulene – Thiophene – Cyanoacrylic acid dyes with donor-π-acceptor structures. Synthesis, characterisation and evaluation in dye-sensitized solar cells". supporting information. p. 2775 - 2786. Retrieved 2018/05/04.