2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-4-hydroxy-9,10-dioxo-, monosodium salt

Base Information

• Chemical Name: 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-4-hydroxy-9,10-dioxo-, monosodium salt
• CAS No.: 25492-62-0
• Molecular Formula: C14H9NO6S.Na
• Molecular Weight: 341.276
• Mol file: 25492-62-0.mol

Synonyms:

Chemical Property of 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-4-hydroxy-9,10-dioxo-, monosodium salt

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-4-hydroxy-9,10-dioxo-, monosodium salt

There total 27 articles about 2-Anthracenesulfonic acid, 1-amino-9,10-dihydro-4-hydroxy-9,10-dioxo-, monosodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

sodium 1-amino-4-bromoanthraquinone-2-sulfonate (6258-06-6) + 4-chloro-aniline (106-47-8) → sodium 1-amino-4-hydroxy-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (25492-62-0) + sodium 1-amino-4-(4-chlorophenylamino)-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (78510-31-3)

Guidance literature:

With disodium hydrogenphosphate; sodium dihydrogenphosphate; copper; In water; at 100 ℃; for 0.0833333h; under 7500.75 Torr; pH=6 - 7; microwave irradiation;

DOI:10.1021/ol070102v

Reference yield: 85.0%

sodium 1-amino-4-bromoanthraquinone-2-sulfonate (6258-06-6) + 4-methoxy-aniline (104-94-9) → sodium 1-amino-4-hydroxy-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (25492-62-0) + sodium 1-amino-4-(4-methoxyphenylamino)-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (63589-10-6)

Guidance literature:

With disodium hydrogenphosphate; sodium dihydrogenphosphate; copper; In water; at 100 ℃; for 0.0833333h; under 7500.75 Torr; pH=6 - 7; microwave irradiation;

DOI:10.1021/ol070102v

Reference yield: 79.0%

sodium 1-amino-4-bromoanthraquinone-2-sulfonate (6258-06-6) + 2-methoxy-phenylamine (90-04-0) → sodium 1-amino-4-hydroxy-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (25492-62-0) + sodium 1-amino-4-(2-methoxyphenylamino)-9,10-dioxo-9,10-dihydroanthracene-2-sulfonate (78510-27-7)

Guidance literature:

With disodium hydrogenphosphate; sodium dihydrogenphosphate; copper; In water; at 100 ℃; for 0.0833333h; under 7500.75 Torr; pH=6 - 7; microwave irradiation;

DOI:10.1021/ol070102v

upstream raw materials:

sodium 1-amino-4-bromoanthraquinone-2-sulfonate

anthranilic acid

2-amino-phenol

4-amino-phenol

Refernces

• 1、 Vinokurov, Yu. V.,Ryabinin, V. A.,Solodova, K. V.,Shein, S. M.. "ELECTROCHEMICAL REDUCTION OF SODIUM 1-AMINO-4-BROMO-ANTHRAQUINONE-2-SULFONATE". . p. 382 - 385. Retrieved 2007/10/02.