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2,2'-Bis(bromomethyl)-1,1'-biphenyl

Base Information Edit
  • Chemical Name:2,2'-Bis(bromomethyl)-1,1'-biphenyl
  • CAS No.:38274-14-5
  • Molecular Formula:C14H12 Br2
  • Molecular Weight:340.057
  • Hs Code.:2903999090
  • European Community (EC) Number:628-317-5
  • NSC Number:73047
  • DSSTox Substance ID:DTXSID90291081
  • Nikkaji Number:J725.711B
  • Wikidata:Q82028915
  • Mol file:38274-14-5.mol
2,2'-Bis(bromomethyl)-1,1'-biphenyl

Synonyms:2,2'-Bis(bromomethyl)-1,1'-biphenyl;38274-14-5;2,2'-Bis(bromomethyl)biphenyl;1-(bromomethyl)-2-[2-(bromomethyl)phenyl]benzene;2,2'-Bis-bromomethyl-biphenyl;1,1'-Biphenyl, 2,2'-bis(bromomethyl)-;NSC73047;2,2'-dibromomethyl-1,1'-biphenyl;2,2-BIS(BROMOMETHYL)-1,1-BIPHENYL;2,2'-dibromomethylbiphenyl;NCIOpen2_008806;o,o'-Bis(bromomethyl)biphenyl;2,2'-di(brommethyl)-diphenyl;o,o'-Bitolyl, a,a'-dibromo-;SCHEMBL1309790;2,2'-bis(bromomethyl)-biphenyl;DTXSID90291081;MFCD00074910;NSC-73047;AKOS015889098;AS-81263;FT-0746744;2,2'-Bis(bromomethyl)-1,1'-biphenyl, 99%;F87358;InChI=1/C14H12Br2/c15-9-11-5-1-3-7-13(11)14-8-4-2-6-12(14)10-16/h1-8H,9-10H

Suppliers and Price of 2,2'-Bis(bromomethyl)-1,1'-biphenyl
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • SynQuest Laboratories
  • 2,2'-Bis(bromomethyl)-1,1'-biphenyl
  • 25 g
  • $ 520.00
  • SynQuest Laboratories
  • 2,2'-Bis(bromomethyl)-1,1'-biphenyl
  • 5 g
  • $ 216.00
  • Sigma-Aldrich
  • 2,2′-Bis(bromomethyl)-1,1′-biphenyl 99%
  • 25g
  • $ 440.00
  • Sigma-Aldrich
  • 2,2′-Bis(bromomethyl)-1,1′-biphenyl 99%
  • 5g
  • $ 121.00
  • Apolloscientific
  • 2,2'-Bis(bromomethyl)-1,1'-biphenyl
  • 5g
  • $ 196.00
  • Apolloscientific
  • 2,2'-Bis(bromomethyl)-1,1'-biphenyl
  • 25g
  • $ 472.00
  • American Custom Chemicals Corporation
  • 2,2-BIS(BROMOMETHYL)-1,1-BIPHENYL 95.00%
  • 25G
  • $ 1509.88
  • American Custom Chemicals Corporation
  • 2,2-BIS(BROMOMETHYL)-1,1-BIPHENYL 95.00%
  • 5G
  • $ 897.07
Total 9 raw suppliers
Chemical Property of 2,2'-Bis(bromomethyl)-1,1'-biphenyl Edit
Chemical Property:
  • Melting Point:90-92 °C(lit.)
     
  • Boiling Point:421.3°Cat760mmHg 
  • Flash Point:244.1°C 
  • PSA:0.00000 
  • Density:1.591g/cm3 
  • LogP:5.14340 
  • XLogP3:4.7
  • Hydrogen Bond Donor Count:0
  • Hydrogen Bond Acceptor Count:0
  • Rotatable Bond Count:3
  • Exact Mass:339.92853
  • Heavy Atom Count:16
  • Complexity:183
Purity/Quality:

98%,99%, *data from raw suppliers

2,2'-Bis(bromomethyl)-1,1'-biphenyl *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes:
  • Statements: 34-36/37 
  • Safety Statements: 26-27-28-36/37/39-45 
MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:
  • Canonical SMILES:C1=CC=C(C(=C1)CBr)C2=CC=CC=C2CBr
  • Uses 2,2′-Bis(bromomethyl)-1,1′-biphenyl was used in the preparation of mononuclear rhodium(III) complex with a nine-membered S, S-chelate ring. It was also used in the preparation of 1,1′-binaphthyl-substituted α-aminoisobutyric acid, a new chiral atropoisomeric α,α-disubstituted glycine.
Technology Process of 2,2'-Bis(bromomethyl)-1,1'-biphenyl

There total 19 articles about 2,2'-Bis(bromomethyl)-1,1'-biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
With hydrogen bromide; In sulfuric acid; water; Heating;
Guidance literature:
In CaCl2; dichloromethane; water;
Guidance literature:
With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; for 24h; Reflux;
DOI:10.1021/acscatal.7b01388
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