Diazenecarbothioamide, N,N-diethyl-2-phenyl-

Base Information

• Chemical Name: Diazenecarbothioamide, N,N-diethyl-2-phenyl-
• CAS No.: 39484-81-6
• Molecular Formula: C11H15N3S
• Molecular Weight: 221.326
• Mol file: 39484-81-6.mol

Synonyms:Diazenecarbothioamide,N,N-diethyl-2-phenyl;N,N-Diethylphenylazothioformamid;N,N-diethyl-(2-phenyldiazenyl)thioformamide;

Chemical Property of Diazenecarbothioamide, N,N-diethyl-2-phenyl-

Chemical Property:

• PSA: 60.05000
• LogP: 3.39700

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Diazenecarbothioamide, N,N-diethyl-2-phenyl-

There total 5 articles about Diazenecarbothioamide, N,N-diethyl-2-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

carbon disulfide (75-15-0,12122-00-8) + diethylamine (109-89-7) + phenylhydrazine (100-63-0) → N,N-diethyl-(2-phenyldiazenyl)thioformamide (39484-81-6)

Guidance literature:

carbon disulfide; phenylhydrazine; In ethanol; for 0.5h; Inert atmosphere;

With potassium hydroxide; In ethanol; for 0.5h; Inert atmosphere;

diethylamine; Further stages;

DOI:10.1080/10610278.2020.1795172

Reference yield:

4,4-diethyl-1-phenylthiosemicarbazide (27421-93-8) → N,N-diethyl-(2-phenyldiazenyl)thioformamide (39484-81-6)

Guidance literature:

With oxygen; diethylamine; at 20 ℃; for 24h;

DOI:10.1021/ma047635t

Reference yield:

phenylhydrazine (100-63-0) → N,N-diethyl-(2-phenyldiazenyl)thioformamide (39484-81-6)

Guidance literature:

Multi-step reaction with 3 steps

1.1: ethanol / 0.25 h

1.2: KOH / ethanol / 0.5 h

2.1: 72 h / Heating

3.1: 53.23 g / oxygen; diethylamine / 24 h / 20 °C

With oxygen; diethylamine; In ethanol;

DOI:10.1021/ma047635t

upstream raw materials:

4,4-diethyl-1-phenylthiosemicarbazide

phenylhydrazine

methyl 2-phenylhydrazinecarbodithioate

carbon disulfide

Refernces

• 1、 Nielsen, Kim T.,Bechgaard, Klaus,Krebs, Frederik C.. "Removal of palladium nanoparticles from polymer materials". . p. 658 - 659. Retrieved 2007/10/03.