2-Chloroethoxytrimethylsilane

Base Information

• Chemical Name: 2-Chloroethoxytrimethylsilane
• CAS No.: 18157-17-0
• Molecular Formula: C5H13 Cl O Si
• Molecular Weight: 152.696
• Hs Code.: 2931900090
• European Community (EC) Number: 628-754-1
• NSC Number: 96781
• DSSTox Substance ID: DTXSID00294467
• Nikkaji Number: J47.882B
• Wikidata: Q63399639
• Mol file: 18157-17-0.mol

Synonyms:2-Chloroethoxytrimethylsilane;18157-17-0;2-chloroethoxy(trimethyl)silane;(2-chloroethoxy)trimethylsilane;(2-chloroethoxy)(trimethyl)silane;NSC96781;Chloroethoxy(trimethyl)silane;2-chloro-ethoxytrimethylsilane;SCHEMBL1095770;Silane,(2-chloroetoxy)trimethyl;2-Chloroethanol, TMS derivative;DTXSID00294467;(2-chloro-ethoxy)-trimethylsilane;2-Chloroethoxytrimethylsilane, 98%;silane, (2-chloroethoxy)trimethyl-;NSC-96781;2-Chloroethanol, trimethylsilyl ether;AKOS006221006;1-CHLORO-2-TRIMETHYLSILOXYETHANE;SILANE,(2-CHLOROETHOXY),TRIMETHYL;FT-0604617;S03850;J-011594;Q63399639;InChI=1/C5H13ClOSi/c1-8(2,3)7-5-4-6/h4-5H2,1-3H

Chemical Property of 2-Chloroethoxytrimethylsilane

Chemical Property:

• Vapor Pressure: 10.2mmHg at 25°C
• Refractive Index: n20/D 1.414(lit.)
• Boiling Point: 134°Cat760mmHg
• Flash Point: 30.6°C
• PSA: 9.23000
• Density: 0.927g/cm³
• LogP: 2.07670
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 152.0424193
• Heavy Atom Count: 8
• Complexity: 59.9

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-Chloroethoxytrimethylsilane 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 16-26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C[Si](C)(C)OCCCl

Technology Process of 2-Chloroethoxytrimethylsilane

There total 9 articles about 2-Chloroethoxytrimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

chloro-trimethyl-silane (75-77-4) + 2-chloro-ethanol (107-07-3) → (2-chloroethoxy)trimethylsilane (18157-17-0)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In dichloromethane; at 5 ℃;

DOI:10.1016/S0040-4039(01)82090-6

Reference yield: 93.0%

2-chloro-ethanol (107-07-3) + allyl-trimethyl-silane (762-72-1) → propene (187737-37-7,13987-01-4,15220-87-8,9003-07-0,676-63-1,25085-53-4) + (2-chloroethoxy)trimethylsilane (18157-17-0)

Guidance literature:

iodine; In chloroform; at 60 ℃; for 0.5h; Mechanism;

DOI:10.1246/cl.1981.85

Reference yield: 86.0%

1,1,1,3,3,3-hexamethyl-disilazane (999-97-3) + 2-chloro-ethanol (107-07-3) → (2-chloroethoxy)trimethylsilane (18157-17-0)

Guidance literature:

for 24h;

DOI:10.1139/v96-164

upstream raw materials:

oxirane

chloro-trimethyl-silane

2-chloro-ethanol

2-methyl-2-phenyl-1,3-dioxolane

Downstream raw materials:

trimethylsilyl fluoride

2-chloroethyl benzenesulfonate

2-(4-nitrophenoxy)ethanol

(4-Chlor-phenyl)-phosphonigsaeure-bis-(2-chlor-ethylester)

Refernces

• 1、 Roos, Christopher,McGibbon, Graham A.,Brook, Michael A.. "The thermolysis of ε-halodisilanes: A preference for 1,2-Si Si→O rearrangement or Si-O cleavage over Si=O bond formation". . p. 1470 - 1479. Retrieved 2007/10/03.
• 2、 Nilolaev, G. A.,Mileshkevich, V. P.,Vainshtein, P. M.,Shmeleva, O. A.. "CATALYTIC REARRANGEMENT REACTIONS BETWEEN CHLORO- AND ALKOXY-SILANES". . p. 1867 - 1870. Retrieved 2007/10/02.