(106Ru)Ruthenium chloride

Base Information

• Chemical Name: (106Ru)Ruthenium chloride
• CAS No.: 63767-78-2
• Molecular Formula: Cl₃Ru
• Molecular Weight: 207.429
• Mol file: 63767-78-2.mol

Synonyms:Ruthenium (106-Ru) chloride;Ruthenium chloride, labeled with ruthenium-106;39290-93-2;Ruthenium chloride (106RuCl3);Ruthenium-106 chloride;(106Ru)Ruthenium chloride;63767-78-2

Chemical Property of (106Ru)Ruthenium chloride

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 210.81389
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: Cl[Ru](Cl)Cl
• Isomeric SMILES: Cl[106Ru](Cl)Cl

Technology Process of (106Ru)Ruthenium chloride

There total 40 articles about (106Ru)Ruthenium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

ruthenium(IV) chloride (13465-52-6) → hydrogenchloride (7647-01-0,15364-23-5) + Ru(4+)*3OH(1-)*Cl(1-)=Ru(OH)3Cl + ruthenium(III)chloride (10049-08-8,63767-78-2)

Guidance literature:

With water; In water; byproducts: Cl2; Cl2 removed by CO2 before hydrolysis completed;;

Reference yield:

ruthenium(III) chloride trihydrate (14898-67-0) → ruthenium(III)chloride (10049-08-8,63767-78-2)

Guidance literature:

In neat (no solvent); 140°C, 48 h;

DOI:10.1021/ja973938+

Reference yield:

chlorine (7782-50-5) + ruthenium (7440-18-8) → ruthenium(III)chloride (10049-08-8,63767-78-2)

Guidance literature:

In neat (no solvent); finely dispersed Ru;;

upstream raw materials:

ruthenium(IV) chloride

ruthenium(III) chloride trihydrate

H⁽¹⁺⁾*{Ru(H₂O)2Cl₄}^(1-)=H{Ru(H₂O)2Cl₄}

H⁽¹⁺⁾*{Ru(H₂O)2Cl₄}^(1-)=H{Ru(H₂O)2Cl₄}

Downstream raw materials:

{Ru(N₃)2(C₂₆H₂₄P₂)2}

RuCl(SnCl₃){Sb(C₆H₅)3}3

carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II)

Ru(II)(TPP⁽¹⁺⁾)(CO)(Cl^(1-))

Refernces

• 1、 Roslova, Maria,Hunger, Jens,Bastien, Ga?l,Pohl, Darius,Haghighi, Hossein M.,Wolter, Anja U. B.,Isaeva, Anna,Schwarz, Ulrich,Rellinghaus, Bernd,Nielsch, Kornelius,Büchner, Bernd,Doert, Thomas. "Detuning the Honeycomb of the α-RuCl3 Kitaev Lattice: A Case of Cr3+ Dopant". . p. 6659 - 6668. Retrieved 2019/05/22.
• 2、 Fu, Shao,Liu, Yongdong,Ding, Yong,Du, Xiaoqiang,Song, Fangyuan,Xiang, Rui,Ma, Baochun. "A mononuclear cobalt complex with an organic ligand acting as a precatalyst for efficient visible light-driven water oxidation". supporting information. p. 2167 - 2169. Retrieved 2014/02/14.