Tetramethylammonium perchlorate

Base Information

• Chemical Name: Tetramethylammonium perchlorate
• CAS No.: 2537-36-2
• Molecular Formula: C8H20N•ClO4
• Molecular Weight: 173.597
• Hs Code.: 29239000
• European Community (EC) Number: 219-805-5
• NSC Number: 245090
• UNII: 6K76T85VMQ
• DSSTox Substance ID: DTXSID5062502
• Wikipedia: Tetramethylammonium perchlorate,Tetramethylammonium_perchlorate
• Wikidata: Q55574159
• Mol file: 2537-36-2.mol

Synonyms:tetraamethylammonium acetate;tetramethylammonium;tetramethylammonium bromide;tetramethylammonium chloride;tetramethylammonium fluoride;tetramethylammonium hydrogen dichloride;tetramethylammonium hydroxide;tetramethylammonium hydroxide pentahydrate;tetramethylammonium iodide;tetramethylammonium nitrate;tetramethylammonium perchlorate;tetramethylammonium sulfate (2:1);tetramethylammonium tribromide;tetramethylammonium triiodide;trimethylaminomethane

Chemical Property of Tetramethylammonium perchlorate

Chemical Property:

• Appearance/Colour: solid
• Melting Point: 300 °C
• Refractive Index: 1.6000 (estimate)
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 74.27000
• Density: g/cm³
• LogP: 0.53670
• Water Solubility.: Soluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 173.0454856
• Heavy Atom Count: 10
• Complexity: 115

Purity/Quality:

99%, ^*data from raw suppliers

TMAPERCHLORATE ^*data from reagent suppliers

Safty Information:

• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 17-36-26

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Perchlorates
• Canonical SMILES: C[N+](C)(C)C.[O-]Cl(=O)(=O)=O
• Uses: Tetramethylammonium perchlorate acts as an intermediate in organic and chemical synthesis. It is used as a mobile phase in high performance liquid chromatographic analysis and in the quantitation of olanzapine clozapine and N-desmethylclozapine. It acts as a supporting electrolyte in the electrochemical reduction of electrochemical reduction of 1-bromodecanr, 1-iododecane,2-iodooctane and 2-bromooctane at mercury cathodes.

Technology Process of Tetramethylammonium perchlorate

There total 10 articles about Tetramethylammonium perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

methanol (67-56-1) + C21H30N4OPbS(2+)*2ClO4(1-) + tetramethyl ammoniumhydroxide (75-59-2,104422-11-9,123626-97-1,154636-59-6,195460-17-4,78017-87-5,93615-68-0,129654-61-1) → Methyl pivalate (598-98-1) + N-((ethylthio)ethyl)-N-((6-amino-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine + tetramethylammonium perchlorate (2537-36-2)

Guidance literature:

methanol; C₂₁H₃₀N₄OPbS⁽²⁺⁾*2ClO₄^(1-); tetramethyl ammoniumhydroxide; at 20 ℃; for 24h;

tetramethyl ammoniumhydroxide; In water; for 0.333333h;

DOI:10.1021/ic401782x

Reference yield:

nitrosonium perchlorate + tetramethylammonium azide (999-77-9) → nitrogen (7727-37-9) + tetramethylammonium perchlorate (2537-36-2) + dinitrogen monoxide (10024-97-2)

Guidance literature:

In liquid sulphur dioxide;

Reference yield:

nitrosonium perchlorate + tetramethlyammonium chloride (75-57-0) → tetramethylammonium perchlorate (2537-36-2) + nitrosylchloride (2696-92-6)

Guidance literature:

In neat (no solvent);

DOI:10.1021/ja01132a055

upstream raw materials:

(methoxymethylidene)dimethylammonium methyl sulfate

N,N-dimethyl-formamide dimethyl acetal

tetramethylammonium bromide

tetramethlyammonium chloride

Downstream raw materials:

formic acid

carbonic-acid

trimethylamine

dihydrogen peroxide

Refernces

• 1、 Goga, Sergey T.,Lebed, Alexander V.,McHedlov-Petrossyan, Nikolay O.. "Conductivity and dissociation constants of quaternary ammonium perchlorates and picrates in 4-methyl-pentan-2-one". body text. p. 1887 - 1892. Retrieved 2011/07/30.