Ethylcyclopropane

Base Information

• Chemical Name: Ethylcyclopropane
• CAS No.: 1191-96-4
• Molecular Formula: C5H10
• Molecular Weight: 70.1344
• Hs Code.: 2902199090
• European Community (EC) Number: 214-746-1
• NSC Number: 2246
• UNII: T5W8NXQ34J
• DSSTox Substance ID: DTXSID4061593
• Nikkaji Number: J132.789E
• Wikidata: Q16322541
• Mol file: 1191-96-4.mol

Synonyms:Ethylcyclopropane;Cyclopropane, ethyl-;1191-96-4;T5W8NXQ34J;NSC 2246;NSC-2246;EINECS 214-746-1;cyclopropylethane;ethyl cyclopropane;NSC2246;UNII-T5W8NXQ34J;DTXSID4061593;AKOS006274304;FT-0693363;Q16322541

Chemical Property of Ethylcyclopropane

Chemical Property:

• Vapor Pressure: 508mmHg at 25°C
• Melting Point: -149.2℃
• Refractive Index: 1.37973 (589.3 nm 18.25℃)
• Boiling Point: 36.2°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 0.772g/cm³
• LogP: 1.80640
• XLogP3: 2.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 70.078250319
• Heavy Atom Count: 5
• Complexity: 27

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Solvents -> Aliphatics, Saturated (
• Canonical SMILES: CCC1CC1

Technology Process of Ethylcyclopropane

There total 21 articles about Ethylcyclopropane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hex-4-enal (2100-19-8) → (Z)-pent-2-ene (627-20-3) + (E)-pent-2-ene (646-04-8) + 1-penten (109-67-1) + ethylcyclopropane (1191-96-4)

Guidance literature:

With Wilkinson's catalyst; In benzene; for 60h; Yield given. Further byproducts given. Yields of byproduct given;

DOI:10.1021/ja00538a021

Reference yield:

(±)-(1-chloroethyl)cyclopropane (10524-06-8) → (Z)-pent-2-ene (627-20-3) + (E)-pent-2-ene (646-04-8) + ethylcyclopropane (1191-96-4)

Guidance literature:

With triphenylstannane; In decalin; at 0 ℃; for 24h; Yield given. Yields of byproduct given; Irradiation;

DOI:10.1039/P29800001473

Reference yield:

(Z)-pent-2-ene (627-20-3) → (E)-pent-2-ene (646-04-8) + methyl-cyclobutane (598-61-8) + ethylcyclopropane (1191-96-4)

Guidance literature:

at 22 ℃; under 20 Torr; Product distribution; Quantum yield; Irradiation; photosensitization by Hg 6(³P₁); equilibrium concentration with the trans-isomer;

upstream raw materials:

1,3-dibromo-pentane

ethyl-(3-bromo-pentyl)-ether

1-(1-cyclopropylethylidene)hydrazine

(+/-)-2-methyl-1-butanol

Downstream raw materials:

erythro-2,3-dibromo-pentane

threo-2,3-dibromo-pentane

1,4-dibromopentane

methylbutane

Refernces

• 1、 Mc Cluskey,Carr. "-". . p. 2637,2639, 2640. Retrieved 1978.
• 2、 Yun, Seongho,Lee, Songhyun,Yook, Sunwoo,Patel, Hasmukh A.,Yavuz, Cafer T.,Choi, Minkee. "Cross-Linked "poisonous" Polymer: Thermochemically Stable Catalyst Support for Tuning Chemoselectivity". . p. 2435 - 2442. Retrieved 2016/04/26.