cis-4-Methyl-2-hexene

Base Information

• Chemical Name: cis-4-Methyl-2-hexene
• CAS No.: 3683-22-5
• Molecular Formula: C7H14
• Molecular Weight: 98.1882
• European Community (EC) Number: 806-420-8,806-422-9
• NSC Number: 73935
• UNII: LFZ9P2BB7S
• DSSTox Substance ID: DTXSID601015951
• Nikkaji Number: J150.260C
• Mol file: 3683-22-5.mol

Synonyms:cis-4-Methyl-2-hexene;(Z)-4-Methyl-2-hexene;4-Methyl-cis-2-hexene;(Z)-4-methylhex-2-ene;3683-19-0;2-Hexene, 4-methyl-, (Z)-;3683-22-5;cis-4-methyl-hex-2-ene;4-Methyl-2-hexene (cis);(2Z)-4-Methyl-2-hexene;(2Z)-4-Methyl-2-hexene #;MBNDKEPQUVZHCM-XQRVVYSFSA-N;DTXSID601015951;(2Z)-4-METHYLHEX-2-ENE;NSC73935;NSC 73932;NSC-73935;AKOS006228469

Chemical Property of cis-4-Methyl-2-hexene

Chemical Property:

• Vapor Pressure: 69mmHg at 25°C
• Melting Point: -125.69°C
• Refractive Index: 1.3998
• Boiling Point: 88.4°C at 760 mmHg
• PSA: 0.00000
• Density: 0.711g/cm³
• LogP: 2.60860
• XLogP3: 3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 98.109550447
• Heavy Atom Count: 7
• Complexity: 53.1

Purity/Quality:

99%min ^*data from raw suppliers

3-Methyl-2-hexene 99% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC(C)C=CC
• Isomeric SMILES: CCC(C)/C=C\C

Technology Process of cis-4-Methyl-2-hexene

There total 3 articles about cis-4-Methyl-2-hexene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

stearic acid (57-11-4) → 2-methyl-2-pentene (625-27-4) + 2-Methyl-1-pentene (763-29-1) + 2,4-dimethyl-1-pentene (2213-32-3) + 3-methyl-2-pentene (922-61-2) + 3-Methyl-cis-2-penten (922-62-3) + trans-4-Octene (14850-23-8) + (Z)-3,4-dimethyl-2-pentene (4914-91-4) + trans-4-Methyl-2-hexene (3683-22-5) + 3-ethyl-2-pentene (816-79-5) + 5-methylhexa-1,4-diene (763-88-2,16483-82-2) + 2,4-dimethyl-3-hexene (82085-14-1) + cis,cis-2,4-Hexadien (6108-61-8)

Guidance literature:

With Ni/HZSM-5 catalysts; at 360 ℃; for 4h;

DOI:10.1039/c6cp06327f

Reference yield:

3-methyl-hexane (589-34-4) → (E)-3-Methyl-hex-2-ene (20710-38-7) + 4-methylhex-1-ene (3769-23-1) + trans-4-Methyl-2-hexene (3683-22-5) + 3-methyl-1-hexene (3404-61-3) + (Z)-3-methyl-3-hexene (4914-89-0) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1)

Guidance literature:

platinum; at 389.9 ℃; Product distribution; selectivity of transformation, ratio of the aromatization in He or H₂ carrier gas and at other temperature; optimum hydrogen pressure for C₅-cyclization and C₅-isomerization;

Reference yield:

4-methyl-2,3-hexadiene (18913-33-2) → trans-4-Methyl-2-hexene (3683-22-5) + cis-4-Methyl-hexen-(2) (3683-19-0)

Guidance literature:

With hydrogen; palladium on barium sulfate;

upstream raw materials:

4-methyl-2,3-hexadiene

3-methyl-hexane

stearic acid

Refernces

• 1、 Zimmer, H.,Paal, Z.,Tetenyi, P.. "CYCLIZATION OF C7-ALKANES OVER Pt BLACK CATALYST". . p. 513 - 532. Retrieved 2007/10/02.