(E)-1-([1,1'-Biphenyl]-2-yl)-N,1-diphenylmethanimine

Base Information

• Chemical Name: (E)-1-([1,1'-Biphenyl]-2-yl)-N,1-diphenylmethanimine
• CAS No.: 51677-34-0
• Molecular Formula: C25H19N
• Molecular Weight: 333.433
• DSSTox Substance ID: DTXSID10532307
• Mol file: 51677-34-0.mol

Synonyms:51677-34-0;(E)-1-([1,1'-Biphenyl]-2-yl)-N,1-diphenylmethanimine;DTXSID10532307

Chemical Property of (E)-1-([1,1'-Biphenyl]-2-yl)-N,1-diphenylmethanimine

Chemical Property:

• XLogP3: 6.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 4
• Exact Mass: 333.151749610
• Heavy Atom Count: 26
• Complexity: 435

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=CC=CC=C2C(=NC3=CC=CC=C3)C4=CC=CC=C4

Technology Process of (E)-1-([1,1'-Biphenyl]-2-yl)-N,1-diphenylmethanimine

There total 6 articles about (E)-1-([1,1'-Biphenyl]-2-yl)-N,1-diphenylmethanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,5-dimethyl-2-phenyl-1,3,2-dioxaborinane (5123-13-7) + C21H20N2 → (2-phenyl-benzhydryliden)-aniline (51677-34-0)

Guidance literature:

With dodecacarbonyl-triangulo-triruthenium; In toluene; at 80 ℃;

DOI:10.1021/acscatal.9b02440

Reference yield:

2-phenylbenzophenone (1985-32-6) + aniline (62-53-3) → (2-phenyl-benzhydryliden)-aniline (51677-34-0)

Guidance literature:

With aniline hydrobromide;

DOI:10.1039/jr9410000478

Reference yield:

2-Biphenylyldiphenylmethylazid (32366-27-1) → (2-phenyl-benzhydryliden)-aniline (51677-34-0) + N-([1,1'-biphenyl]-2-yl)-1,1-diphenylmethanimine (51677-35-1)

Guidance literature:

In cyclohexane; at 25 ℃; for 24h; Thermodynamic data; Mechanism; Irradiation; difference in activation energy for phenyl and 2-biphenylyl groups to migrate;

DOI:10.1021/ja00522a049

upstream raw materials:

N-(2-methoxy-α-phenylbenzylidene)aniline

2-phenylbenzophenone

aniline

2-Biphenylyldiphenylmethylazid

Refernces

• 1、 Kyba, Evan P.,Abramovitch, Rudolph A.. "Photolysis of Alkyl Azides. Evidence for a Nonnitrene Mechanism". . p. 735 - 740. Retrieved 2007/10/02.