Tetrahydrofurfuryl methacrylate

Base Information

• Chemical Name: Tetrahydrofurfuryl methacrylate
• CAS No.: 2455-24-5
• Deprecated CAS: 125166-24-7,160211-89-2,64461-15-0,160211-89-2,64461-15-0
• Molecular Formula: C9H14 O3
• Molecular Weight: 170.208
• Hs Code.: 29321900
• European Community (EC) Number: 219-529-5
• NSC Number: 32634
• UNII: 120GN9C472
• DSSTox Substance ID: DTXSID0022191
• Nikkaji Number: J208.715D
• Wikidata: Q20054551
• ChEMBL ID: CHEMBL3561338
• Mol file: 2455-24-5.mol

Synonyms:methacrylic acid tetrahydrofurfuryl ester;tetrahydrofurfuryl methacrylate;THFM-A

Chemical Property of Tetrahydrofurfuryl methacrylate

Chemical Property:

• Vapor Pressure: 0.0094mmHg at 25°C
• Refractive Index: n20/D 1.458(lit.)
• Boiling Point: 52 °C0.4 mm Hg(lit.)
• Flash Point: 91 ºC
• PSA: 35.53000
• Density: 1.044
• LogP: 1.28470
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• Sensitive.: Light Sensitive
• Water Solubility.: 18.99g/L at 20℃
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 170.094294304
• Heavy Atom Count: 12
• Complexity: 186

Purity/Quality:

99%min ^*data from raw suppliers

Tetrahydrofurfuryl methacrylate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Hazard Codes: R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.
• Statements: 10-36/37/38
• Safety Statements: 36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Plastics & Rubber -> (Meth)acrylates
• Canonical SMILES: CC(=C)C(=O)OCC1CCCO1
• Uses: Tetrahydrofurfuryl methacrylate is used as methacrylic component in dental materials, such as crown and bridge products; in artificial nails.

Technology Process of Tetrahydrofurfuryl methacrylate

There total 4 articles about Tetrahydrofurfuryl methacrylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

Tetrahydrofurfuryl alcohol (97-99-4) + methacrylic acid methyl ester (80-62-6,114512-63-9,143476-91-9,25188-98-1,9011-14-7) → (tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate (2455-24-5,25035-85-2)

Guidance literature:

With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide; In 2-Methylpentane; cyclohexane; at 85 - 100 ℃; for 12h; Temperature;

Reference yield:

Tetrahydrofurfuryl alcohol (97-99-4) + poly(methacrylic acid) (79-41-4,25087-26-7,50867-57-7) → (tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate (2455-24-5,25035-85-2)

Guidance literature:

With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In dichloromethane; at 20 ℃;

DOI:10.1002/anie.201904707

Reference yield:

Tetrahydrofurfuryl alcohol (97-99-4) + methyl methacrylate (97-63-2,9003-42-3) → (tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate (2455-24-5,25035-85-2)

Guidance literature:

With sulfuric acid;

DOI:10.1021/jo01158a019

upstream raw materials:

Tetrahydrofurfuryl alcohol

methyl methacrylate

methacrylic acid methyl ester

poly(methacrylic acid)

Downstream raw materials:

(tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-oxo-4-phenylbutanoate

Refernces

• 1、 -. "PROCESS FOR PREPARING 4-HYDROXYBUTYL ACRYLATE". Paragraph 0635; 0636; 0637; 0638; 0639. . Retrieved 2015/04/22.
• 2、 -. "Disinfectant polymeric coatings for hard surfaces". . . Retrieved 2008/06/13.