Nitrogen sulfide

Base Information

• Chemical Name: Nitrogen sulfide
• CAS No.: 12033-56-6
• Molecular Formula: NS
• Molecular Weight: 46.0727
• DSSTox Substance ID: DTXSID50923331
• Nikkaji Number: J1.386.190K
• Wikipedia: Sulfur_mononitride
• Mol file: 12033-56-6.mol

Synonyms:Nitrogen sulfide;Nitrogen sulfide (NS);12033-56-6;nitrogen monosulfide;mononitrogen monosulfide;NS radical;CHEBI:29451;DTXSID50923331;NS(.);(NS)(.)

Chemical Property of Nitrogen sulfide

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 0
• Exact Mass: 45.97514518
• Heavy Atom Count: 2
• Complexity: 2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [N]=S

Technology Process of Nitrogen sulfide

There total 5 articles about Nitrogen sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogen sulfide (7783-06-4) + nitrogen (7727-37-9) → poly(sulfur nitride) (12033-56-6) + heptathiazocine (293-42-5) + sulfur (7704-34-9)

Guidance literature:

reaction of H2S with active nitrogen; products deposited on the walls;

DOI:10.1021/ic50029a018

Reference yield:

S3N4C (112749-70-9) → poly(sulfur nitride) (12033-56-6) + tetrasulphur tetranitride (127770-66-5) + tetrasulphur dinitride (79796-31-9) + Dicyano-diazene (1557-57-9)

Guidance literature:

In neat (no solvent); vac. thermolysis at 70°C and <1E-5 Torr for 24 h;

DOI:10.1039/c39870001611

Reference yield:

thiophosphoryl triazide (4635-47-6) → hydrogen azide (7782-79-8) + poly(sulfur nitride) (12033-56-6) + phosphorus nitride (17739-47-8) + dinitrogen sulfide (67200-92-4)

Guidance literature:

heated to 1000°C; deposited onto cold matrix; detd. by IR;

DOI:10.1002/anie.201108636

upstream raw materials:

hydrogen sulfide

nitrogen

sulfur

dinitrogen disulphide

Downstream raw materials:

disulfur

dinitrogen disulphide

tetrasulphur dinitride

(S₃N₃)

Refernces

• 1、 Zeng, Xiaoqing,Beckers, Helmut,Willner, Helge,Francisco, Joseph S.. "Experimental observation of the 16-electron molecules SPN, SNP, and cyclic PSN". . p. 3334 - 3339. Retrieved 2012/06/15.
• 2、 Banister, Arthur J.,Clegg, William,Gorrell, Ian B.,Hauptman, Zdenek V.,Small, Ronald W. H.. "Reactions of S3N2Cl2 and (NSCl)3 with a new Silylcyanamide Reagent (Me3Si)2N.CN: Synthesis and X-Ray Crystal Structure of and Bicyclic CClS3N5". . p. 1611 - 1613. Retrieved 2007/10/02.