Cyclohexane, 1-propenyl-

Base Information

• Chemical Name: Cyclohexane, 1-propenyl-
• CAS No.: 5364-83-0
• Molecular Formula: C9H16
• Molecular Weight: 124.226
• Nikkaji Number: J113.148F
• Mol file: 5364-83-0.mol

Synonyms:Cyclohexane, 1-propenyl-;Cyclohexane, propenyl-;5364-83-0;1-Propenylcyclohexane;Propenylcyclohexane;(1-propenyl)cyclohexane;1-Cyclohexyl-1-propene;Propene, 1-cyclohexyl-;1-Propene, 1-cyclohexyl-;(1E)-1-Propenylcyclohexane #;IAHIMVFWYADCJJ-QHHAFSJGSA-N;AKOS015907105;BS-22068;Ethyl2-amino-4-phenyl-1H-pyrrole-3-carboxylate

Chemical Property of Cyclohexane, 1-propenyl-

Chemical Property:

• Vapor Pressure: 4.23mmHg at 25°C
• Boiling Point: 153.7oC at 760 mmHg
• Flash Point: 32oC
• PSA: 0.00000
• Density: 0.872g/cm3
• LogP: 3.14280
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 124.125200510
• Heavy Atom Count: 9
• Complexity: 86.2

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC=CC1CCCCC1
• Isomeric SMILES: C/C=C/C1CCCCC1

Technology Process of Cyclohexane, 1-propenyl-

There total 31 articles about Cyclohexane, 1-propenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.1%

(R*,S*)-2-Diphenylphosphinoyl-1-cyclohexylpropan-1-ol (88533-71-5,88533-79-3,103786-03-4,103786-04-5) → (Z)-prop-1-en-1-ylcyclohexane (2114-41-2,5364-83-0,37490-34-9)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; at 50 ℃; for 1h;

DOI:10.1016/S0040-4039(00)94318-1

Reference yield: 54.0%

5-(ethylsulfonyl)-1-phenyl-1H-tetrazole (3206-46-0) + cyclohexanecarbaldehyde (2043-61-0) → 1-cyclohexylprop-1-ene (5364-83-0)

Guidance literature:

With potassium hexamethylsilazane; In tetrahydrofuran; at -78 ℃; for 0.5h;

DOI:10.1002/chem.200600180

Reference yield:

1-phenyl-acetone (103-79-7,136675-26-8) → 1-cyclohexylprop-1-ene (5364-83-0) + 1-cyclohexyl-2-propanol (76019-86-8)

Guidance literature:

With hydrogen; palladium on activated charcoal;

DOI:10.1039/b110937p

upstream raw materials:

cyclohexylpropyl alcohol

1-bromocyclohexane

2-chloropropionyl chloride

1-phenyl-acetone

Downstream raw materials:

propylcyclohexane

threo-1-cyclohexyl-2-methyl-4-phenyl-3-butyn-1-ol

1-cyclohexylpropane-1,2-diol

benzoic acid

Refernces

• 1、 -. "METHODS OF BORYLATION AND USES THEREOF". Page/Page column 61-62. . Retrieved 2021/04/30.
• 2、 Yu, Xiaolong,Zhao, Haonan,Li, Ping,Koh, Ming Joo. "Iron-Catalyzed Tunable and Site-Selective Olefin Transposition". supporting information. p. 18223 - 18230. Retrieved 2020/12/04.