Breithauptite

Base Information

• Chemical Name: Breithauptite
• CAS No.: 12125-61-0
• Molecular Formula: Ni₀Sb₀
• Molecular Weight: 61.2124
• DSSTox Substance ID: DTXSID60153203
• Wikipedia: Breithauptite
• Wikidata: Q18211982
• Mol file: 12125-61-0.mol

Synonyms:Breithauptite;CCRIS 7588;12125-61-0;Ni-Sb;Breithauptite (NiSb);nickel(III) antimonide;DTXSID60153203;MFCD00050100;LS-45220;Copper Selenide (CuSe) Sputtering Targets;Q18211982

Chemical Property of Breithauptite

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Density: g/cm³
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 178.83915
• Heavy Atom Count: 2
• Complexity: 10

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Safety Statements: Suspected carcinogen. When heated to decomposition it emits toxic vapors of Ni and Sb.:

MSDS Files:

Useful:

• Canonical SMILES: [Ni]#[Sb]

Technology Process of Breithauptite

There total 27 articles about Breithauptite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

sodium antimonide + nickel dichloride (83864-14-6) → nickel antimonide (12035-52-8,12125-61-0,12503-49-0)

Guidance literature:

In ammonia; byproducts: NaCl, Ni; NH3 (liquid); from NiCl2 and Na3Sb in molar ratio 3:2 by stirring at room temp. in liq. NH3 for 36 h; trituration with water and CS2; annealing at 250-300°C for 48 h; powder XRD, SEM/EDXA, Raman-, IR-spectroscopies;

DOI:10.1021/ic010648s

Reference yield: 75.0%

sodium antimonide + nickel dibromide (13462-88-9) → nickel antimonide (12035-52-8,12125-61-0,12503-49-0)

Guidance literature:

In toluene; byproducts: NaBr, Ni; under N2; toluene added to powdered Na3Sb, powdered NiBr2 added under stirring, ratio of Ni salt/Na pnictide = 3:2, heated at reflux for 48 h under stirring; slurry was allowed to settle, toluene syringed off, solid washed subsequently with ethanol, water, and ethanol, annealed at 500°C for 48 h;

DOI:10.1016/S0277-5387(00)00323-5

Reference yield:

antimony (7440-36-0) + nickel dichloride (83864-14-6) → NiSb, γ (12035-52-8,12125-61-0,12503-49-0) + nickel (7440-02-0)

Guidance literature:

With KBH₄; In ethylenediamine; Sonication; Sb, NiCl2, KBH4 and ethylenediamine ultrasonically mixed, heated at 140°C for 24 h; detd. by X-ray powder diffraction;

DOI:10.1006/jssc.2000.8889

upstream raw materials:

antimony

nickel

antimony(III) chloride

nickel dichloride

Downstream raw materials:

nickel antimonide

Refernces

• 1、 Meschel, S. V.,Nash, Philip. "Enthalpies of formation of some 3d Transition Metal-Antimony compounds by high temperature direct synthesis calorimetry". . . Retrieved 2020.
• 2、 Markovski, Slobodan L.,Micke, Kornelia,Richter, Klaus W.,Van Loo, Frans J.J.,Ipser, Herbert. "Phase relationships in the ternary Ga-Ni-Sb system". . p. 128 - 136. Retrieved 2000.
• 3、 Fan, Guilan,Xu, Wence,Li, Jinhan,Chen, Jia-Liang,Yu, Meng,Ni, Youxuan,Zhu, Shengli,Su, Xun-Cheng,Cheng, Fangyi. "Nanoporous NiSb to Enhance Nitrogen Electroreduction via Tailoring Competitive Adsorption Sites". . . Retrieved 2021/09/06.