Ruthenium tribromide

Base Information

• Chemical Name: Ruthenium tribromide
• CAS No.: 14014-88-1
• Molecular Formula: Br3Ru
• Molecular Weight: 340.782
• European Community (EC) Number: 237-829-4
• Wikipedia: Ruthenium(III)_bromide
• Wikidata: Q4096894
• Mol file: 14014-88-1.mol

Synonyms:Ruthenium tribromide;14014-88-1;Ruthenium bromide (RuBr3);Tribromoruthenium;Ruthenium(III) bromide, Ru 29%;MFCD00016314;CS-0084418;Q4096894

Chemical Property of Ruthenium tribromide

Chemical Property:

• Vapor Pressure: 20200mmHg at 25°C
• Melting Point: decomposes at >400℃ [LID94]
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: g/cm³
• LogP: 2.53680
• Sensitive.: Hygroscopic
• Water Solubility.: Insoluble in water.
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 340.65730
• Heavy Atom Count: 4
• Complexity: 8

Purity/Quality:

98%min ^*data from raw suppliers

Ruthenium(III) bromide hydrate ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: Br[Ru](Br)Br
• Uses: Ruthenium(III) bromide is used in chemical research.

Technology Process of Ruthenium tribromide

There total 5 articles about Ruthenium tribromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ruthenium tetroxide (20427-56-9) + hydrogen bromide (10035-10-6,12258-64-9) → ruthenium(III) bromide (14014-88-1)

Guidance literature:

In not given; A Cl2-free soln. of RuO4 is warmed with HBr and a few drops of alc. on a water bath;; crystn. on evapn.;;

Reference yield:

bromine (7726-95-6) + ruthenium (7440-18-8) → ruthenium(III) bromide (14014-88-1)

Guidance literature:

In neat (no solvent); reaction for 30 to 35 h in sealed tube (Mo or pyrex glass) at 450 to 500°C, ampuls are heated in autoclave filled with N2 or CO2 at 20 atue;;

Reference yield:

ruthenium trichloride hydrate (14898-67-0) + hydrogen bromide (10035-10-6,12258-64-9) → ruthenium(III) bromide (14014-88-1)

Guidance literature:

threefold evapn. with conc. HBr;

upstream raw materials:

ruthenium trichloride hydrate

hydrogen bromide

bromine

ruthenium

Downstream raw materials:

RuHBr(CO)[P(C₆H₅)3]3

ruthenium

bromine

Refernces

• 1、 Kukushkin,Bavina,Zinchenko. "Conversion of Oximes Involving Ruthenium Compounds". . p. 1553 - 1554. Retrieved 2007/10/03.