Triisobutylphosphine sulphide

Base Information

• Chemical Name: Triisobutylphosphine sulphide
• CAS No.: 3982-87-4
• Deprecated CAS: 119683-82-8
• Molecular Formula: C12H27 P S
• Molecular Weight: 234.386
• European Community (EC) Number: 223-621-0
• NSC Number: 222464
• UNII: 53AW9L5CH6
• DSSTox Substance ID: DTXSID80890567
• Nikkaji Number: J217.813C
• Wikidata: Q72513598
• Mol file: 3982-87-4.mol

Synonyms:Triisobutylphosphine sulfide;3982-87-4;Triisobutylphosphine sulphide;Phosphine sulfide, tris(2-methylpropyl)-;Tris(2-methylpropyl)phosphine sulfide;EINECS 223-621-0;tris(2-methylpropyl)-sulfanylidene-lambda5-phosphane;NSC 222464;NSC-222464;TIBPS;NSC222464;Cyanex 471X;53AW9L5CH6;Phosphine sulfide, triisobutyl-;SCHEMBL2549960;DTXSID80890567;tris(2-methylpropyl)--phosphanethione;AKOS025295290;tris(2-methylpropyl)-sulfanylidenephosphorane;Triisobutylphosphine sulfide, >=97.0% (CHN);tris(2-methylpropyl)-sulfanylidene-5-phosphane;TRIS(2-METHYLPROPYL)-??-PHOSPHANETHIONE

Chemical Property of Triisobutylphosphine sulphide

Chemical Property:

• Vapor Pressure: 0.00409mmHg at 25°C
• Melting Point: 57-60 °C
• Boiling Point: 288.3°Cat760mmHg
• Flash Point: 128.1°C
• PSA: 41.90000
• Density: 0.902g/cm³
• LogP: 5.08450
• XLogP3: 5.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 6
• Exact Mass: 234.15710903
• Heavy Atom Count: 14
• Complexity: 161

Purity/Quality:

98%, ^*data from raw suppliers

TRIISOBUTYLPHOSPHINE SULFIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/38
• Safety Statements: 22-26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(C)CP(=S)(CC(C)C)CC(C)C
• Uses: Triisobutylphosphine Sulphide is a toxic organic solvent used in microbial fermentation.

Technology Process of Triisobutylphosphine sulphide

There total 1 articles about Triisobutylphosphine sulphide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

isobutylmagnesium bromide (926-62-5) → tri-i-butylphosphine sulfide (3982-87-4)

Guidance literature:

With tetraphosphorus decasulfide; diethyl ether;

Reference yield: 95.0%

tri-i-butylphosphine sulfide (3982-87-4) → P(i-C4H9)3O (7682-87-3)

Guidance literature:

With perfluoro-cis-2-n-butyl-3-n-propyloxaziridine; In various solvent(s); for 0.0833333h; Ambient temperature; further reagent;

DOI:10.1021/jo970572a

upstream raw materials:

isobutylmagnesium bromide

Downstream raw materials:

P(i-C4H9)3O