(3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE

Base Information

• Chemical Name: (3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE
• CAS No.: 59501-41-6
• Molecular Formula: C18H20O2
• Molecular Weight: 268.356
• Mol file: 59501-41-6.mol

Synonyms:4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol;bisphenol A monoallyl ether;Phenol,4-[1-methyl-1-[4-(2-propenyloxy)phenyl]ethyl];4-<1-(4-Allyloxyphenyl)-1-methylethyl>-phenol;

Chemical Property of (3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE

Chemical Property:

• PSA: 29.46000
• LogP: 4.28290

Purity/Quality:

99% ^*data from raw suppliers

4-(2-(4-(Allyloxy)phenyl)propan-2-yl)phenol 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE

There total 9 articles about (3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

BPA (80-05-7) + Allyl ether (557-40-4) → 2-allyl-4-(2-(4-hydroxyphenyl)propane-2-yl)phenol (109348-07-4) + 2,2-bis(3-allyl-4-hydroxyphenyl)propane (1745-89-7) + C21H24O2 (105577-85-3) + 4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol (59501-41-6) + bisphenol A diallyl ether (3739-67-1)

Guidance literature:

BPA; With chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium (II); silver(I) 4-methylbenzenesulfonate; toluene-4-sulfonic acid; In toluene; for 0.0833333h; Inert atmosphere;

Allyl ether; In toluene; at 60 ℃; for 3h; Inert atmosphere;

DOI:10.1002/aoc.1743

Reference yield: 25.0%

BPA (80-05-7) + allyl alcohol (107-18-6) → 2-allyl-4-(2-(4-hydroxyphenyl)propane-2-yl)phenol (109348-07-4) + 2,2-bis(3-allyl-4-hydroxyphenyl)propane (1745-89-7) + C21H24O2 (105577-85-3) + 4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol (59501-41-6) + bisphenol A diallyl ether (3739-67-1)

Guidance literature:

BPA; With silver(I) 4-methylbenzenesulfonate; toluene-4-sulfonic acid; In toluene; for 0.0833333h; Inert atmosphere;

allyl alcohol; In toluene; at 80 ℃; for 3h; Inert atmosphere;

DOI:10.1002/aoc.1743

Reference yield: 24.0%

BPA (80-05-7) + Allyl ether (557-40-4) → 4-(2-(4-(allyloxy)phenyl)propane-2-yl)phenol (59501-41-6) + bisphenol A diallyl ether (3739-67-1)

Guidance literature:

BPA; With (2,2-dimethylpropane-1,3-diyl)bis(diphenylphosphane); palladium diacetate; In toluene; for 0.0833333h; Inert atmosphere;

Allyl ether; In toluene; at 100 ℃; for 20h; Inert atmosphere;

DOI:10.1002/aoc.1743

upstream raw materials:

BPA

Allyl acetate

3-chloroprop-1-ene

Allyl ether

Downstream raw materials:

1-(2,2-diethyl-4-methylcyclobutoxy)-4-(2-(4-(prop-1-en-1-yloxy)-phenyl)propan-2-yl)benzene

C₁₈H₂₀O₂

triethoxy(3-(2-(oxirane-2-ylmethoxy)-5-(2-(4-(oxirane-2-ylmethoxy)phenyl)propane-2-yl)phenyl)propyl)silane

2-((2-allyl-4-(2-(4-(oxirane-2-ylmethoxy)phenyl)propane-2-yl)phenoxy)methyl)oxirane

Refernces

• 1、 -. "ALKOXYSILYL COMPOUND HAVING AT LEAST TWO ALKOXYSILYL GROUPS, COMPOSITION, CURED PRODUCT THEREOF, USE THEREOF AND PREPARING METHOD OF ALKOXYSILYL COMPOUND HAVING AT LEAST TWO ALKOXYSILYL GROUPS". Paragraph 0775 - 0777. . Retrieved 2016/12/07.
• 2、 -. "EPOXY COMPOUND HAVING ALKOXYSILYL GROUP, METHOD OF PREPARING THE SAME, COMPOSITION AND CURED PRODUCT COMPRISING THE SAME, AND USES THEREOF". Paragraph 0407; 0408. . Retrieved 2014/07/08.