N-Ethyl-N-methylmorpholinium bromide

Base Information

• Chemical Name: N-Ethyl-N-methylmorpholinium bromide
• CAS No.: 65756-41-4
• Molecular Formula: C7H16NO+
• Molecular Weight: 210.112
• Hs Code.: 2934999090
• European Community (EC) Number: 418-250-8
• NSC Number: 133318
• DSSTox Substance ID: DTXSID80886304
• Mol file: 65756-41-4.mol

Synonyms:1-ethyl-1-methylmorpholinium bromide;4-Ethyl-4-methylmorpholinium bromide;65756-41-4;N-Ethyl-N-methylmorpholinium bromide;4-ethyl-4-methylmorpholin-4-ium bromide;N-Methyl-N-ethylmorpholinium bromide;Morpholinium, 4-ethyl-4-methyl-, bromide;MethylEthylMorpholiniumBromide;4-ethyl-4-methylmorpholin-4-ium;bromide;Morpholinium, 4-ethyl-4-methyl-, bromide (1:1);EC 418-250-8;N-methyl ,ethyl-Morpholinium bromide;4-Ethyl-4-methylmorpholin-4-iumbromide;C(C)N1(C)CCOCC1;SCHEMBL2536007;DTXSID80886304;MFCD03095385;NSC133318;N-methyl-N-ethyl morpholinium bromide;AKOS016010586;NSC 133318;NSC-133318;AC-27456;AS-64103;CS-0187004;E1166;D90597;A855130;J-515289

Chemical Property of N-Ethyl-N-methylmorpholinium bromide

Chemical Property:

• Melting Point: 170oC
• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: g/cm³
• LogP: -2.55410
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: Methanol (Slightly), Water (Slightly)
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 209.04153
• Heavy Atom Count: 10
• Complexity: 86.9

Purity/Quality:

99.9% ^*data from raw suppliers

4-Ethyl-4-methylmorpholinium Bromide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 68
• Safety Statements: 36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC[N+]1(CCOCC1)C.[Br-]

Technology Process of N-Ethyl-N-methylmorpholinium bromide

There total 1 articles about N-Ethyl-N-methylmorpholinium bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

4-methyl-morpholine (109-02-4) + ethyl bromide (74-96-4) → N-ethyl-N-methylmorpholinium bromide (65756-41-4)

Guidance literature:

In methanol; at 0 - 55 ℃; Inert atmosphere;

DOI:10.1002/pola.24008

Reference yield: 80.0%

bis(trifluoromethane)sulfonimide lithium (90076-65-6) + N-ethyl-N-methylmorpholinium bromide (65756-41-4) → N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide salt (706785-83-3)

Guidance literature:

In dichloromethane; for 24h;

DOI:10.1039/b400198b

upstream raw materials:

4-methyl-morpholine

ethyl bromide

Downstream raw materials:

N-ethyl-N-methylmorpholinium bis(trifluoromethanesulfonyl)imide salt

Refernces

• 1、 Lu, Benlian,Xu, Airong,Wang, Jianji. "Cation does matter: How cationic structure affects the dissolution of cellulose in ionic liquids". . p. 1326 - 1335. Retrieved 2014.
• 2、 Marcinkowski, Lukasz,Olszewska, Teresa,Kloskowski, Adam,Warminska, Dorota. "Apparent molar volumes and expansivities of ionic liquids based on N -Alkyl- N -methylmorpholinium cations in acetonitrile". . p. 718 - 725. Retrieved 2014/04/03.