Peroxydisulfuryl difluoride

Base Information

• Chemical Name: Peroxydisulfuryl difluoride
• CAS No.: 13709-32-5
• Molecular Formula: F2O6S2
• Molecular Weight: 198.125
• DSSTox Substance ID: DTXSID801312731
• Nikkaji Number: J706.587F
• Wikipedia: Peroxydisulfuryl difluoride
• Mol file: 13709-32-5.mol

Synonyms:13709-32-5;PEROXYDISULFURYL DIFLUORIDE;Peroxydisulfuryl fluoride;Bis(fluorosulfonyl) peroxide;DTXSID801312731;I(1/4)-Peroxo-bis(fluorodioxosulfur)

Chemical Property of Peroxydisulfuryl difluoride

Chemical Property:

• XLogP3: 0.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 3
• Exact Mass: 197.91043639
• Heavy Atom Count: 10
• Complexity: 239

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: O=S(=O)(OOS(=O)(=O)F)F

Technology Process of Peroxydisulfuryl difluoride

There total 17 articles about Peroxydisulfuryl difluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sulfur trioxide (7446-11-9) + fluorine (7782-41-4) → bis(fluorosulfuryl) peroxide (13709-32-5)

Guidance literature:

SO3-excess, high temp.;

DOI:10.1021/ja01560a002

Reference yield:

sulfur trioxide (7446-11-9) + fluorine (7782-41-4) → fluorosulfuryl hypofluorite (13536-85-1) + bis(fluorosulfuryl) peroxide (13709-32-5)

Guidance literature:

Irradiation (UV/VIS); 70-110 °C, λ=365 nm; Kinetics;

Reference yield:

fluorosulphonic acid (7789-21-1) → bis(fluorosulfuryl) peroxide (13709-32-5)

Guidance literature:

at 56 ℃; for 2h; Electrochemical reaction; Inert atmosphere;

upstream raw materials:

fluorosulfuryl hypofluorite

sulfur dioxide

dioxygen difluoride

sulfur trioxide

Downstream raw materials:

trisulfuryl fluoride

manganese tris(fluorosulfate)

dioxorhenium(VII) tris(fluorosulfate)

Br⁽³⁺⁾*6SO₃F^(1-)*Au⁽³⁺⁾=[Br(SO₃F)2][Au(SO₃F)4]

Refernces

• 1、 Brown, S. D.,Gard, G. L.. "". . p. 19 - 21. Retrieved 1975.
• 2、 Bernhardt, Eduard,Bach, Christian,Bley, Bianca,Wartchow, Rudolf,Westphal, Ulrich,Sham, Iona H.T.,Von Ahsen, Britta,Wang, Chanqing,Willner, Helge,Thompson, Robert C.,Aubke, Friedhelm. "Homoleptic, σ-bonded octahedral [M(CO)6]2+ cations of iron(II), ruthenium(II), and osmium(II): Part 1: Syntheses, thermochemical and vibrational characterizations, and molecular structures as [Sb2F11]- and [SbF6]- salts. A comprehensive, comparative study". . p. 4189 - 4205. Retrieved 2005.
• 3、 Cobos,Croce. "Evidences for a new ultraviolet absorption band of the FSO3 radical". . p. 897 - 909. Retrieved 2008/10/09.