cis-1-Propenyl isopropyl ether

Base Information

• Chemical Name: cis-1-Propenyl isopropyl ether
• CAS No.: 4188-64-1
• Molecular Formula: C6H12O
• Molecular Weight: 100.1589
• Nikkaji Number: J789.026E
• Mol file: 4188-64-1.mol

Synonyms:cis-1-Propenyl isopropyl ether;1-Propene, 1-(1-methylethoxy)-, (Z)-;4188-64-1;(Z)-1-Isopropoxy-propene;cis-isopropyl propenyl ether;SCHEMBL891317;(Z)-1-Isopropoxy-1-propene;(1Z)-1-Isopropoxy-1-propene;PLGKZYGGZOMZHL-PLNGDYQASA-N;(1Z)-1-Isopropoxy-1-propene #

Chemical Property of cis-1-Propenyl isopropyl ether

Chemical Property:

• Vapor Pressure: 63.5mmHg at 25°C
• Boiling Point: 90.4°Cat760mmHg
• Flash Point: °C
• PSA: 9.23000
• Density: 0.782g/cm³
• LogP: 1.94500
• XLogP3: 1.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 100.088815002
• Heavy Atom Count: 7
• Complexity: 55.2

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC=COC(C)C
• Isomeric SMILES: C/C=C\OC(C)C

Technology Process of cis-1-Propenyl isopropyl ether

There total 2 articles about cis-1-Propenyl isopropyl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3-isopropoxyprop-1-ene (6140-80-3) → 1c-isopropoxy-propene (4188-64-1)

Guidance literature:

In dimethyl sulfoxide; at 75 - 170 ℃; Equilibrium constant; Thermodynamic data; ΔG(excit.), ΔH(excit.), ΔS(excit.);

DOI:10.1016/S0040-4020(01)81820-2

Reference yield:

→ 1c-isopropoxy-propene (4188-64-1)

Guidance literature:

Aus entspr. Acetal;

DOI:10.1021/ja00464a023

Reference yield: 62.0%

1c-isopropoxy-propene (4188-64-1) + p-tolylsulfonylallene (16192-08-8) → 1-[(2S,3R)-3-Isopropoxy-2-methyl-cyclobut-(E)-ylidenemethanesulfonyl]-4-methyl-benzene

Guidance literature:

In dichloromethane; at 50 ℃; for 16h; under 11251100 Torr;

DOI:10.1002/ejoc.200390135

upstream raw materials:

3-isopropoxyprop-1-ene

Downstream raw materials:

3-isopropoxyprop-1-ene

Refernces

• 1、 Matsuhashi, Hiromi,Hattori, Hideshi,Tanabe, Kozo. "DOUBLE BOND MIGRATION OF ALLYL ETHERS OVER SOLID BASE CATALYSTS". . p. 341 - 342. Retrieved 2007/10/02.